Error message

  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).

Alkali and Magnetite-Modified Fly Ash for Adsorption of Naphthol Blue Black Dye: Characterization, Performance, Isothermal and Kinetic Studies

Aprilina Purbasari1, Restu Kusumawardani1, Dessy Ariyanti1, Noer Abyor Handayani1
Affiliation: 
1 Department of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro, Jl. Prof. Jacub Rais, Kampus Tembalang, Semarang 50275, Indonesia aprilina.purbasari@che.undip.ac.id
DOI: 
https://doi.org/10.23939/chcht20.01.110
AttachmentSize
PDF icon full_text.pdf745.27 KB

Keywords:

Abstract: 
Wastewater containing dyes at certain levels can be harmful to the environment. Removal of dye pollutants in wastewater can be done by the adsorption method. Fly ash, solid waste from coal combustion, can be utilized as a dye adsorbent. Modification of fly ash with alkali (NaOH solution) and magnetite (Fe3O4) can increase the adsorption capacity and facilitate separation. In this paper, fly ash was modified with alkali and magnetite and then applied as an adsorbent for naphthol blue black (NBB) dye. The highest efficiency of NBB dye adsorption by alkali and magnetite-modified fly ash was 99.17%. Adsorption followed the Freundlich isotherm model and the pseudo-second-order kinetics model.
References: 

[1] Ali, I.; Asim, M.; Khan, T.A. Low Cost Adsorbents for The Removal of Organic Pollutants from Wastewater. J. Environ. Manage. 2012, 113, 170-183. https://doi.org/10.1016/j.jenvman.2012.08.028
https://doi.org/10.1016/j.jenvman.2012.08.028

[2] Yao, Z.T.; Ji, X.S.; Sarker, P.K.; Tang, J.H.; Ge, L.Q.; Xia, M.S.; Xi, Y.Q. A Comprehensive Review on The Applications of Coal Fy Ash. Earth Sci. Rev. 2015, 141, 105-121. https://doi.org/10.1016/j.earscirev.2014.11.016
https://doi.org/10.1016/j.earscirev.2014.11.016

[3] Purbasari, A.; Ariyanti, D.; Sumardiono S; Khairunnisa, K.; Sidharta, T. Adsorption Kinetics and Isotherms of Cu(II) and Fe(II) Ions from Aqueous Solutions by Fly Ash-Based Geopolymer. Chem. Chem. Technol. 2022, 16, 169-176. https://doi.org/10.23939/chcht16.02.169
https://doi.org/10.23939/chcht16.02.169

[4] Li, F.; Wu, W.; Li, R.; Fu, X. Adsorption of Phosphate by Acid-Modified Fly Ash and Palygorskite in Aqueous Solution: Experimental and Modeling. Appl. Clay Sci. 2016, 132-133, 343-352. https://doi.org/10.1016/j.clay.2016.06.028
https://doi.org/10.1016/j.clay.2016.06.028

[5] Nguyen, T.C.; Tran, T.D.M.; Dao, V.B.; Vu, Q.T.; Nguyen, T.D.; Thai, H. Using Modified Fly Ash for Removal of Heavy Metal Ions from Aqueous Solution. J. Chem. 2020, 2020, 8428473. https://doi.org/10.1155/2020/8428473
https://doi.org/10.1155/2020/8428473

[6] Purbasari, A.; Ariyanti, D.; Sumardiono, S.; Shofa, M.A.; Manullang, R.P. Comparison of Alkali Modified Fly Ash and Alkali Activated Fly Ash as Zn(II) Ions Adsorbent from Aqueous Solution. Sci. Sinter. 2022, 54, 49-58. https://doi.org/10.2298/SOS2201049P
https://doi.org/10.2298/SOS2201049P

[7] Gita, S.; Hussan, A.; Choudhury, T.G. Impact of Textile Dyes Waste on Aquatic Environments and Its Treatment. Environ. Ecol. 2017, 35(3C), 2349-2353.

[8] Naz, S.; Kiran, S.; Gulzar, T.; Farooq, T. The Photocatalytic Performance of Co3O4/Na-Alginate Nanocomposite for The Dynamic Removal of Direct Red 31 Dye: Degradation and Mechanical Pathways. Glob. NEST J. 2024, 26, 06199. https://doi.org/10.55555/gnj.006199

[9] Benammar, H.S.; Guergazi, S.; Youcef, S.; Youcef, L. Removal of Congo Red and Naphthol Blue Black Dyes from Aqueous Solution by Adsorption on Activated Carbon. Characterization, Kinetic and Equilibrium in Nonlinear Models Studies. Desalin. Water Treat. 2021, 221, 396-405. https://doi.org/10.5004/dwt.2021.27031
https://doi.org/10.5004/dwt.2021.27031

[10] Julinawati, J.; Febriani, F.; Mustafa, I.; Fathurrahmi, F.; Rahmi, R.; Sheilatina, S.; Ahmad, K.; Puspita, K.; Iqhrammullah, M. Tryptophan-Based Organoclay for Aqueous Naphthol Blue Black Removal - Preparation, Characterization, and Batch Adsorption Studies. J. Ecol. Eng. 2023, 24, 274-284. https://doi.org/10.12911/22998993/165781
https://doi.org/10.12911/22998993/165781

[11] Lubis, S.; Sheilatina, S.; Nika, S.S.; Putra, V.P. Adsorption of Naphthol Blue Black Dye onto Acid Activated Titania Pillared Bentonite: Equilibrium Study. Orient. J. Chem. 2016, 32, 1789-1797. https://doi.org/10.13005/ojc/320407
https://doi.org/10.13005/ojc/320407

[12] Nahurskyi, N.; Malovanyy, M.; Bordun, I.; Szymczykiewicz, E. Magnetically Sensitive Carbon-Based Nanocomposites for The Removal of Dyes and Heavy Metals from Wastewater: A Review. Chem. Chem. Technol. 2024, 18, 170-186. https://doi.org/10.23939/chcht18.02.170
https://doi.org/10.23939/chcht18.02.170

[13] Amodu, O.S.; Ojumu, T.V.; Ntwampe, S.K.; Ayanda, O.S. Rapid Adsorption of Crystal Violet onto Magnetic Zeolite Synthesized from Fly Ash and Magnetite Nanoparticles. J. Encapsul. Adsorpt. Sci. 2015, 5, 191-203. https://doi.org/10.4236/jeas.2015.54016
https://doi.org/10.4236/jeas.2015.54016

[14] Harja, M.; Buema, G.; Lupu, N.; Chiriac, H.; Herea, D.D.; Ciobanu, G. Fly Ash Coated with Magnetic Materials: Improved Adsorbent for Cu (II) Removal from Wastewater. Materials 2021, 14, 63. https://doi.org/10.3390/ma14010063
https://doi.org/10.3390/ma14010063

[15] Yamaura, M.; Fungaro, D.A. Synthesis and Characterization of Magnetic Adsorbent Prepared by Magnetite Nanoparticles and Zeolite from Coal Fly Ash. J. Mater. Sci. 2013, 48, 5093-5101. https://doi.org/10.1007/s10853-013-7297-6
https://doi.org/10.1007/s10853-013-7297-6

[16] Jasper, E.E.; Ajibola, V.O.; Onwuka, J.C. Nonlinear Regression Analysis of The Sorption of Crystal Violet and Methylene Blue from Aqueous Solutions onto an Agro‑Waste Derived Activated Carbon. Appl. Water Sci. 2020, 10, 132. https://doi.org/10.1007/s13201-020-01218-y
https://doi.org/10.1007/s13201-020-01218-y

[17] López‑Luna, J.; Ramírez‑Montes, L.E.; Martinez‑Vargas, S.; Martínez, A.I.; Mijangos‑Ricardez, O.F.; González‑Chávez, M.C.A.; Carrillo‑González, R.; Solís‑Domínguez, F.A.; Cuevas‑Díaz, M.C.; Vázquez‑Hipólito, V. Linear and Nonlinear Kinetic and Isotherm Adsorption Models for Arsenic Removal by Manganese Ferrite Nanoparticles. SN Appl. Sci. 2019, 1, 950. https://doi.org/10.1007/s42452-019-0977-3
https://doi.org/10.1007/s42452-019-0977-3

[18] Ngakou, C.S.; Anagho, G.S.; Ngomo H.M. Non-Linear Regression Analysis for The Adsorption Kinetics and Equilibrium Isotherm of Phenacetin onto Activated Carbons. Curr. J. Appl. Sci. Technol. 2019, 36, 1-18. https://doi.org/10.9734/CJAST/2019/v36i430246
https://doi.org/10.9734/cjast/2019/v36i430246

[19] Konanets, R; Stepova, K. Nonlinear Isotherm Adsorption Modelling for Copper Removal from Wastewater by Natural and Modified Clinoptilolite and Glauconite. Chem. Chem. Technol. 2024, 18, 94-102. https://doi.org/10.23939/chcht18.01.094
https://doi.org/10.23939/chcht18.01.094

[20] Purbasari, A.; Ariyanti, D.; Sumardiono, S.; Masyaroh, M.; Salsabila, T.R. Physical Properties and Structural Characteristics of Alkali Modified Fly Ash. J. Phys. Conf. Ser. 2021, 1912, 012012. https://doi.org/10.1088/1742-6596/1912/1/012012
https://doi.org/10.1088/1742-6596/1912/1/012012

[21] Sotomayor, F.J.; Cychosz, K.A.; Thommes M. Characterization of Micro/Mesoporous Materials by Physisorption: Concepts and Case Studies. Acc. Mater. Surf. Res. 2018, 3, 34-50.

[22] Yuan, N.; Cai, H.; Liu, T.; Huang, Q.; Zhang, X. Adsorptive Removal of Methylene Blue from Aqueous Solution Using Coal Fly Ash-Derived Mesoporous Silica Material. Adsorpt. Sci. Technol. 2019, 37, 333-348. https://doi.org/10.1177/0263617419827438f
https://doi.org/10.1177/0263617419827438

[23] Kang, J.; Parsons, J.; Gunukula, S.; Tran, D.T. Iron and Magnesium Impregnation of Avocado Seed Biochar for Aqueous Phosphate Removal. Clean Technol. 2022, 4, 690-702. https://doi.org/10.3390/cleantechnol4030042
https://doi.org/10.3390/cleantechnol4030042

[24] Rosa, T.; Martins, A.; Santos, M.T.; Trindade, T.; Nunes, N. Coal Fly Ash Waste, A Low-Cost Adsorbent for The Removal of Mordant Orange Dye from Aqueous Media. J. Braz. Chem. Soc. 2021, 32, 2245-2256. https://doi.org/10.21577/0103-5053.20210116
https://doi.org/10.21577/0103-5053.20210116

[25] Wang, J.; Guo, X. Adsorption Isotherm Models: Classification, Physical Meaning, Application and Solving Method. Chemosphere 2020, 258, 127279. https://doi.org/10.1016/j.chemosphere.2020.127279
https://doi.org/10.1016/j.chemosphere.2020.127279

[26] Supelano G.I.; Cuaspud J.A.G.; Moreno-Aldana L.C.; Ortiz C.; Trujillo C.A.; Palacio C.A.; Vargas C.A.P.; Gómez J.A.M. Synthesis of Magnetic Zeolites from Recycled Fly Ash for Adsorption of Methylene Blue. Fuel 2020, 263, 116800. https://doi.org/10.1016/j.fuel.2019.116800
https://doi.org/10.1016/j.fuel.2019.116800

[27] Malek, N.N.A.; Jawad, A.H.; Ismail, K.; Razuan, R.; ALOthman, Z.A. Fly Ash Modified Magnetic Chitosan-Polyvinyl Alcohol Blend for Reactive Orange 16 Dye Removal: Adsorption Parametric Optimization. Int. J. Biol. Macromol. 2021, 189, 464-476. https://doi.org/10.1016/j.ijbiomac.2021.08.160
https://doi.org/10.1016/j.ijbiomac.2021.08.160

[28] Karthika, M.; Vasuki, M. Comparative Study of Adsorption of Different Dyes from Aqueous Media onto Physically Activated Carbon: Isotherm, Kinetic and Thermodynamic Parameter. Int. J. Appl. Eng. Res. 2021, 16, 441-446.

[29] Benjelloun, M.; Miyah, Y.; Evrendilek, G.A.; Zerrouq, F.; Lairini, S. Recent Advances in Adsorption Kinetic Models: Their Application to Dye Types. Arab. J. Chem. 2021, 14, 103031. https://doi.org/10.1016/j.arabjc.2021.103031
https://doi.org/10.1016/j.arabjc.2021.103031