Calculation Method of Heat Capacity Change during Organic Compounds Vaporization and Sublimation
Affiliation:
Lviv Polytechnic National University
12 S.Bandery St., 79013 Lviv, Ukraine; phys.chem.lp@gmail.com
DOI:
https://doi.org/10.23939/chcht10.01.027
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Keywords:
Abstract:
On the basis of literature data the constancy of heat capacity change during vaporization ( 2 %) and sublimation ( 8 %) has been determined at 298 K for different organic compounds. The obtained equations allow to recalculate the enthalpy according to Kirchhoff’s law easier compared with present techniques based on the increments method. The vaporization and sublimation enthalpies of 5-(2-nitrophenyl)-furan-2-carbaldehyde have been determined and recalculated for 298 K for the reliability proofing of the suggested method.
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