Error message

  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).

Obtaining of Functional Surface Active Monomers Based on tert-Butylperoxy-6-hydroxyhexanoate

Mykola Borzenkov, Larysa Dolynska, Viktoriia Kochubei, Zoriana Nadashkevich and Orest Hevus
Affiliation: 
Lviv Polytechnic National University 12, Bandera str., 79013 Lviv, Ukraine
DOI: 
https://doi.org/10.23939/chcht05.04.363
AttachmentSize
PDF icon full_text.pdf100.42 KB

Keywords:

Abstract: 
The interaction of -caprolactone with tert-butylhydroperoxide led to tert-butylperoxyhexanoate. Peroxymaleinate has been obtained by the reaction of tert-butylperoxyhexanoate with a maleic anhydride. Functional monomers have been synthesized by reactions of peroxymaleinate with propansultone and polyethylene glycol (PEG). The obtained compounds exhibit surface active properties, reducing a surface tension at the water-air interface.
References: 

[1] Kohut A., Fleychuk R., Hevus O. et al.: Macromolecular Symposia, 2007, 254, 117.
https://doi.org/10.1002/masy.200790047

[2] Kohut A., Hevus O. and Voronov S.: Visnuk DU "Lvivska polytechnika", 1998, 339, 59.

[3] Hevus O., Kohut A. and Fleychuk R.: Abstracts of III Polish-Ukrainian Conference on "Polymers of Special Applications", 2004, 16.

[4] Harold A., Shoonbrood S. and Jose M.: Macromolecules, 1997, 30, 6034.
https://doi.org/10.1021/ma9701494

[5] Kohut A., Ranjian S., Voronov A. and Hevus O.: Langmuir, 2006, 22, 6498.
https://doi.org/10.1021/la060162u

[6] Kohut A., Hevus O. and Voronov S.: Langmuir, 2006, 22, 1946.
https://doi.org/10.1021/la052225z

[7] Pich A., Datta S. and Adler H.-J.: Polymer, 2005, 4, 1323.
https://doi.org/10.1016/j.polymer.2004.11.065

[8] Kohut A., Hevus O. and Voronov S.: J. Appl. Polymer Sci, 2004, 93, 310.
https://doi.org/10.1002/app.20456

[9] Vuitsyk L., Mitina N., Skorohid N. et al.: Nanostrukturnoe Materialovedenie, 2008, 12, 1109.

[10] Kohut A., Fleychuk R. and Hevus O.: Chem. & Chem. Techn., 2007, 1, 83.

[11] Fleychuk R. and Hevus O.: Visnuk NU "Lvivska polytechnika", 2003, 488, 120.

[12] Fleychuk R. and Hevus O.: Zh. Org. Khimii, 2003, 12, 1870.

[13] Montoya-Goni A. and Sherrington D.: Polymer, 1999, 40, 1359.
https://doi.org/10.1016/S0032-3861(98)00356-5

[14] Borzenkov M., Dolinska L., Nadashkevich Z. and Hevus O.: Visnuk NU "Lvivska polytechnika", 2010, 667, 59.

[15] Havkins J.: Organiceskie Perekisi. Khimiya, Moskwa 1964.

[16] Knunianc I.: Chimiceskyi Encuklopediceskyi Slovar. Sov. Encuklopedia, Moskwa 1983.

[17] Starcher P. and Phillips B.: J. Am. Chem. Soc, 1958, 80, 4079.
https://doi.org/10.1021/ja01548a063

[18] Weissberger A. and Proskauer E.: Organiceskie Rastvoriteli. Inost. lit, Moskwa 1958.

[19] Antonovskyi V. and Buzanov M.: Analiticiskaya Khimiya Organiceskich Peroksidnyh Soedinenyi. Khimiya, Moskwa 1978.

[20] Cheroniks N. and Ma T.: Micro-i Polumicrometody Organiceskogo Funkcionalnogo Analiza. Khimiya, Moskwa 1973.

[21] Abramzon A. and Zaichenko L.: Poverchnostno-Aktivnye Veshestva. Sintez, Analiz, Svoistva i Preminenie. Khimiya, Leningrad 1988.