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Obtaining of Functional Surface Active Monomers Based on tert-Butylperoxy-6-hydroxyhexanoate

Mykola Borzenkov, Larysa Dolynska, Viktoriia Kochubei, Zoriana Nadashkevich and Orest Hevus
Affiliation: 
Lviv Polytechnic National University 12, Bandera str., 79013 Lviv, Ukraine
DOI: 
https://doi.org/10.23939/chcht05.04.363
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Abstract: 
The interaction of -caprolactone with tert-butylhydroperoxide led to tert-butylperoxyhexanoate. Peroxymaleinate has been obtained by the reaction of tert-butylperoxyhexanoate with a maleic anhydride. Functional monomers have been synthesized by reactions of peroxymaleinate with propansultone and polyethylene glycol (PEG). The obtained compounds exhibit surface active properties, reducing a surface tension at the water-air interface.
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