Functionalization of Isobutylene Oligomers and 1,2-Polybutadiene with Methyldiazoacetate in the Presence of Cu(OAc)2-2,4-Lut-ZnCl2 Catalytic System
Affiliation:
1 Institute of Organic Chemistry of the Ufa Centre of Science of the Russian Academy of the Science,
71 Oktiabria ave, 450054 Ufa, Russia; dokichev@anrb.ru
2 Bashkir State University, 32 Zaki Validi str., 450005 Ufa, Russia
3Emmanuel Institute of Biochemical Physics of the Russian Academy of the Science,
4 Kosygina str., 119334 Moscow, Russia; GEZaikov@yahoo.com.
DOI:
https://doi.org/10.23939/chcht05.02.181
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Abstract:
A catalytic method of the chemical modification of isobutylene oligomers and syndiotactic 1,2-polybutadiene on the C=C bond via the [1+2] cycloaddition of metoxycarbonylcarbene in the presence of Cu(OAc)2-2,4-Lut-ZnCl2 is proposed.
References:
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