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Functionalization of Isobutylene Oligomers and 1,2-Polybutadiene with Methyldiazoacetate in the Presence of Cu(OAc)2-2,4-Lut-ZnCl2 Catalytic System

Rimma Sultanova1, Raisa Biglova2, Tagir Yangirov2, Vladimir Dokichev1 and Gennady Zaikov3
Affiliation: 
1 Institute of Organic Chemistry of the Ufa Centre of Science of the Russian Academy of the Science, 71 Oktiabria ave, 450054 Ufa, Russia; dokichev@anrb.ru 2 Bashkir State University, 32 Zaki Validi str., 450005 Ufa, Russia 3Emmanuel Institute of Biochemical Physics of the Russian Academy of the Science, 4 Kosygina str., 119334 Moscow, Russia; GEZaikov@yahoo.com.
DOI: 
https://doi.org/10.23939/chcht05.02.181
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Keywords:

Abstract: 
A catalytic method of the chemical modification of isobutylene oligomers and syndiotactic 1,2-polybutadiene on the C=C bond via the [1+2] cycloaddition of metoxycarbonylcarbene in the presence of Cu(OAc)2-2,4-Lut-ZnCl2 is proposed.
References: 

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[9] Gareev V., Sultanova R., Biglova R. et al.: Bull. Rossijskoi Academii Nauk, 2008, 8, 1610.