Error message

  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).

Vaporization and Sublimation Enthalpies of Six Carbone-12 Peroxide Containing Derivatives

Volodymyr Dibrivnyi, Natalya Boutylina, Galyna Melnyk, Yurij Raevskyi and Yurij Van-Chin-Syan
Affiliation: 
Department of Physical and Colloidal Chemistry, Lviv Polytechnic National University, 12, S. Bandery str., 79013 Lviv, Ukraine; Vdibriv@polynet.lviv.ua
DOI: 
https://doi.org/10.23939/chcht04.02.085
AttachmentSize
PDF icon full_text.pdf100.77 KB
Abstract: 
Vaporization and sublimation enthalpies of six peroxide containing derivatives of carboranes were obtained on the basis of temperature dependencies of the saturated vapor pressure that was measured by Knudsen effusion method. Fusion enthalpies were defined by DSC method. The inputs of carborane nuclei and the increments of the hydrogen atom deputies groups in carboranes were determined.
References: 

[1] Zvereva T., Yuvchenko A. and Zhukovskaya N.: Russ. Zh. Org. Khim., 1992, 62, 143.

[2] Ol'dekop Yu., Churkina L. and Zvereva T.: Russ. Zh Org. Khim., 1978, 48, 574.

[3] Dibrivnyi V., Lutsiv G. and Van-Chin-Syan Yu.: Russ. Zh. Fiz. Khim., 1999, 73, 2254.

[4] Gal'chenko G.: [in:] Gerasimov Ya. and Akishin P. (Eds.), Khimicheskaya Termodinamika. Izd-vo Mosk. Gos. Univ., Moskwa 1984.

[5] Tamm N.: PhD thesis. Moskovsky Gosudarstvenny Universitet, Moskwa 1994.

[6] Lebedev Yu. and Miroshnichenko E.: Termokhimiya Ispareniya Organicheskih Soedinenij. Nauka, Moskwa 1981.

[7] Van-Chin-Syan Yu.: Doctoral thesis. Moskovsky Gosudarstvenny Universitet, Moskwa 1986.

[8] Chickoks J. and Acree W.: J. Phys. Chem., 2003, 32, 519.
https://doi.org/10.1063/1.1529214