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Kinetic model of photoinitiated copolymerization of monofunctional monomers till high conversions

Yuriy Medvedevskikh, Galyna Khovanets’ and Iryna Yevchuk
Affiliation: 
Department of Physical Chemistry of Combustible Minerals L. M. Lytvynenko Institute of Physico-Organic Chemistry and Coal Chemistry NAS of Ukraine 3a Naukova str., 79053 Lviv, Ukraine vfh@org.lviv.net
DOI: 
https://doi.org/10.23939/chcht03.01.001
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Keywords:

Abstract: 
Regularities of kinetics of photoinitiated copolymerization till high conversions in the systems of monofunctional methacrylate comonomers (hydroxyethyl methacrylate (HEMA), glycidyl methacrylate (GMA)) have been investigated by laser interferometry in a wide range of experimental factors (molar ratio of comonomers, photoinitiator concentration, intensity of UV-irradiation). Kinetic model of photoinitiated copolymerization of methacrylates till high conversions has been proposed on the basis of microheterogeneity conception of the polymerization process.
References: 

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