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Reaction kinetics and macromolecule-metal chelate complex formation in metal containing semi-interpenetrating polymer networks based on crosslinked polyurethane and linear polymethylmethacrylate

Ludmila Kosyanchuk, Nataly Kozak, Oksana Antonenko, Yury Nizelskii and Yury Lipatov
DOI: 
https://doi.org/10.23939/chcht02.04.263
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Abstract: 
According to DSC and EPR data kinetics of formation of simultaneous semi-interpenetrating polymer networks based on crosslinked polyurethane and linear polymethylmethacrylate with 50:50 and 70:30 ratio obtained in the presence of 3d-metal chelates depends on type of metal. On the other hand system composition determines polyurethane or polymethylmethacrylate selection during formation of complexes with metal -diketonates.
References: 

[1] Lipatov Yu.: Vzaimopronikaushchie polimernye setki s razdelennymi phazami. Dnepropetrovsk 2001.

[2] Lee J., Ruegg M., Balsara N. et al.: Macromolecules, 2003, 36, 6537.
https://doi.org/10.1021/ma0340356

[3] Aravind I., Albert P., Ranganathaiah C. et al.: Polymer, 2004, 45, 4925.
https://doi.org/10.1016/j.polymer.2004.04.063

[4] Jien-Ming H.: J. Appl. Polym. Sci., 2003, 88, 2247.
https://doi.org/10.1002/app.11945

[5] Alekseeva T., Lipatov Yu., Babkina N. et al.: Polymer, 2005, 46, 319.
https://doi.org/10.1016/j.polymer.2004.05.063

[6] Nizelskii Yu.: Cataliticheskie svoistva -diketonatov metalov. Naukova dumka, Kyiv 1983.

[7] Shklyaev A. and Anufrienko V.: Zh. Struct. Khim., 1975, 16, 999.
https://doi.org/10.1007/BF00747883

[8] Kozak N., Kosyanchuk L., Lipatov Yu., et al.: Vysokomol. Soed., 2000, 42(A), 2104.

[9] Lipatov Yu., Kosyanchuk L., Kozak N. et al.: Vysokomol. Soed., 2006, 48(A), 388.
https://doi.org/10.1134/S0965545X06040079

[10] Lipatov Yu., Alekseeva T. and Rosovitsky V.: Doklady Akad. Nauk SSSR, 1989, 307, 883.

[11] Buchachenko A., Kovarskii A. and Vasserman A. [in:] Rogovin Z. (ed.) Study of polymers by the paramagnetic probe methods. Advances in polymer science. Wiley, NY 1974.

[12] Lipatova T. and Nizelskii Yu. [in:] Uspekhi khimii polyuretanov: komplexoobrazovanie I mehanizm cataliza reakcii obrazovanoya uretanov -diketonatami medi. Naukova Dumka, Kyiv 1972.

[13] Lipatov Yu., Kosyanchuk L., Babkina N. et al.:Dopovidi Nats. Akad. Nauk Ukrainy, 2005, 7, 134.

[14] Lipatov Yu. and Alekseeva T.: Uspekhi khimii, 1992, 61, 1203.
https://doi.org/10.1070/RC1992v061n12ABEH001026

[15] Gladyshev G. and Popov V.: Radikalnaya polymerizaziya pri glubokih stepenyah prevrasheniya. Nauka, Moskva 1974.

[16] Guryanova E., Goldshtein I. and Romm I.: Donorno-akceptornye svyazi. Khimiya, Moskva 1973.

[17] Day M. and Selbin J.: Theoretical inorganic chemistry (3rd ed.). Reinhold Book Corp., NY-Amsterdam-London 1969.

[18] Giesielski W., Lii Ch., Ven M.-T. and Tomasik P.: Carbohydrate Polymers, 2003, 51, 47.
https://doi.org/10.1016/S0144-8617(02)00108-X