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The studies of complex formation of metal borides in the reaction system of epoxidation of 1-octene with tert-butyl hydroperoxide by IR spectroscopy

Oksana Makota and Yuriy Trach
DOI: 
https://doi.org/10.23939/chcht01.03.127
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Abstract: 
The complex formation of molybdenum and vanadium borides in the reaction system of 1-octene epoxidation with tert-butyl hydroperoxide by infrared spectroscopic analysis was studied. It was shown that 1-octene formed complex with metal moiety in a case of molybdenum boride and with boron moiety in a case of vanadium boride.
References: 

[1] A.K. Yudin.: Aziridines and epoxides in organic synthesis. Wiley-VCH, Weinheim, Germany, 2006.
https://doi.org/10.1002/3527607862

[2] K. Weissermel, H.-J. Arpe. Industrial organic chemistry, Wiley-VCH, Weinheim, Germany, 2003.
https://doi.org/10.1002/9783527619191

[3] Applied homogeneous catalysis with organometallic compounds. Editors Cornils B., Herrmann W.A.: Wiley-VCH, Weinheim, Germany, 2002. Vol. 1.

[4] Peroxide Chemistry. Mechanistic and preparative aspects of oxygen transfer. Editor W. Adam.: Wiley-VCH, Weinheim, Germany, 2000.

[5] Yu. B. Trach, O.I. Makota, M.V. Nikipanchuk, I.Yu. Pyrig, R.G. Makitra.: Petroleum Chemistry, 2003, 43, 424-427.

[6] Yu. B. Trach, O.I. Makota.: Petroleum Chemistry, 2004, 44, 48-51.

[7] Yu. B. Trach, O.I. Makota.: Petroleum Chemistry, 2005, 45, 327-329.

[8] Yu.Trach, B.Schulze, O.Makota, L.Bulgakova.: Journal of Molecular Catalysis A: Chemical, 2006, 258, 292-294.
https://doi.org/10.1016/j.molcata.2006.05.069

[9] T.S. Sian, G.B. Reddy.: Solid state ionics, 2004, 167, 399-405.
https://doi.org/10.1016/j.ssi.2004.01.005

I. Ardelean, M. Toderas, P. Pascuta.: Modern phisics letters B, 2003, 17, No. 22, 1175-1179
https://doi.org/10.1142/S0217984903006098