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Kinetics and Products of 4-Aminotoluene Oxidization by Ozone in the Liquid Phase

Andrey Bushuyev, Michael Keremet, Andrey Galstyan and Tatyana Galstyan
Affiliation: 
Volodymyr Dahl East Ukrainian National University (Rubizhne city), Ukraine; bas131982@mail.ru
DOI: 
https://doi.org/10.23939/chcht09.01.043
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Keywords:

Abstract: 
The kinetic regularities and mechanisms of oxidation reactions of 4-aminotoluene and its acylation derivatives by the gases that contain ozone in the glacial acetic acid have been studied. The process of liquid-phase catalytic oxidation of 4-acetaminotoluene by ozone in the presence of transition metal salts and their mixtures with potassium bromide to the corresponding acetaminobenzoic acid has been investigated.
References: 

[1] Galstyan G., Tyupalo N. and Galstyan A.: Zhidkofaznoe Kataliticheskoe Okislenie Aromaticheskikh Soedineniy Ozonom. VNU im. V. Dalya, Lugansk 2009.

[2] Spanggord R., Yao C. and Mill D.: Environ. Sei. Technol., 2000, 34, 497.
https://doi.org/10.1021/es990190h

[3] Spanggord R. and Clizbe L.: J. Labelled Compd. Radiopharm., 1998, 41, 615.
https://doi.org/10.1002/(SICI)1099-1344(199807)41:7<615::AID-JLCR106>3.0.CO;2-B

[4] Ronald J. and David Yao C.: Environ. Sci. Technol., 2000, 34, 497.
https://doi.org/10.1021/es990190h

[5] Andrzejewski P., Kasprzyk-Hordern B., Jeleň H. and Hawrocki J.: Ochrona Środowiska, 2007, 29, 11.

[6] Zahardis J. and Geddes S.: Petrucci Atmos. Chem. Phys. Discuss., 2007, 7, 14603.
https://doi.org/10.5194/acpd-7-14603-2007

[7] Galstyan A., Bushuev A. and Solomyanniy R.: Ukr. Khim. Zh., 2008, 74, 57.

[8] Bailey P.: Ozonation in Organic Chemistry, Vol. 2. Academic Press, NY 1982.

[9] Bailey P., Rice R. and Cotruvo J.: Cleveland: Int. Ozone Inst., 1975, 1, 101.

[10] Criegee R.: Chem. Zeitung, 1975, 3, 138.

[11] Criegee R.: Chimia, 1968, 22, 392.

[12] Razumovskiy S. and Zaikov G.: Ozon i ego Reakcii s Organicheskimi Soedineniyami. Nauka, Moskwa 1974.

[13] Galstyan G., Galstyan T. and Mikulenko L.: Kinetika i Kataliz,1994, 35, 255.

[15] Galstyan G., Galstyan A. and Andreev P.: Vestnik Fizioterapii i Kulturologii, 2005, 11, 157.

[16] Galstyan A. and Sedyih A.: Kinetika i Kataliz, 2009, 50, 698.

[17] Galstyan G., Potapenko E., Pluzhnik I. et al.: Proceed. Regional Conf. on Ozone Generation & Application to Water & Waster Treatment. Russia, Moskow 1998, 667.

[18] Beletskaya I. and Mahonkov D.: Uspekhi Khimii, 1981, 50, 1007.
https://doi.org/10.1070/RC1981v050n06ABEH002649

[19] Emanuel N.: Neftekhimiya, 1978, 18, 485.

[20] Zaharov I. and Galetiy Yu.: ibid, 615.

[21] Emanuel N. and Knorre D.: Kurs Khimicheskoy Kinetiki. Vyshaya Shkola, Moskwa 1969.