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Effect of the Reactants Molar Ratio on the Kinetics of the Reaction to Obtain 2-hydroxyethyl-1,3,4 trimethyl-cyclohex-3-encarboxylate

Irina Kostiv1, Olga Marshalok1, Galyna Marshalok2 and Igor Pyrig1
Affiliation: 
1Lviv Polytechnic National University 12, S. Bandery str.,79013 Lviv, Ukraine 2Jan and Jędrzej Śniadecki University of Technology and Life Sciences in Bydgoszcz Ks. Kordecki Str. 20, 85-225 Bydgoszcz, Poland
DOI: 
https://doi.org/10.23939/chcht09.03.277
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Abstract: 
Kinetic aspects of the reaction of 2-hydroxyethyl-1,3,4-trimethylcyclohex-3-ene-1-carboxylate obtaining have been investigated. On the basis of the obtained results the kinetics of the process has been studied by the Michaelis-Menten equation. The limiting stage of the reaction is established and its mechanism is suggested.
References: 

[1] Voet D. and Voet J.: Biochemistry 4th edn., Wiley, NY 2011.

[2] Polyova I., Marshalok G., Fedevych M. et al.: UA Pat. 46772, MPK С 07 С 11/00. Publ. Jan. 11, 2010.

[3] Polyova I., Marshalok G., Fedevych M. et al.: UA Patent 52884, MPK С 07 С 11/00. Publ. Sept. 10, 2010.

[4] Polyova І., Polyuzhin I., Marshalok G. and Gladii A.: III Vseukr. Nauk. Konf. Stud. i Asp. "Khimichny Karazinski Chitaniya 2011," Kharkov 2011, 41.

[5] Shmid R. and Sapunov V.: Neformal'naya Kinetika. Mir, Moskwa 1985.

[6] Jasinski R., Kwiatnowska M. and Baranski A.: Wiadom. Chemiczne, 2007, 61, 485-514.

[7] Woodward R. and KatzT.: Tetrahedron, 1959, 5, 70-89.

[8] Ross S. and Kuntz J.: J. Am. Chem. Soc., 1954, 76, 3000-3012.

[9] Hammett L.: Physical Organic Chemistry. McGraw-Hill, New York 1970.

[10] Marshalok G., Oglashennyi Yu., Makitra R. and Yatchishin I.: Zh. Org. Khim., 2003, 39, 1221-1226.

[11] Makitra R., Tsikanchuk Ya. and Turkevich O.: Dokl. Akad. Nauk SSSR, 1976, 5, 435-437.