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Kinetic Aspects of Catalytic Interactions Involving Pentyl Acetate and Ethanolamine

Stepan Melnyk1, Yurii Melnyk1, Halyna Mahorivska1, Olena Fuchyla1
Affiliation: 
1 Lviv Polytechnic National University, 12, Bandera St., 79013 Lviv, Ukraine stepan.r.melnyk@lpnu.ua
DOI: 
https://doi.org/10.23939/chcht17.04.820
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Keywords:

Abstract: 
A conversion scheme for pentyl acetate, ethanolamine, and the products resulting from their interaction through aminolysis, transesterification, and O-N-acyl migration reactions catalyzed by homogeneous and heterogeneous Brønsted-Lowry bases and acids is proposed. It has been determined that acid and base catalysts significantly enhance the aminolysis reaction of esters with amino alcohols when compared to the non-catalytic process. The impact of the catalyst on each reaction has been assessed.
References: 

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[18] Melnyk, S.; Danyliuk, R.; Melnyk, Yu.; Stadnytska, N. Study of the Pentyl Acetate and Ethanolamine Catalytic and Non-Catalytic Interaction. J. Chem. Technol. Metall. 2022, 57, 439-450.

[19] Melnyk S.R.; Danyliuk R.V.; Melnyk Yu.R. Ethanolamine and Pentyl Acetate Interaction Catalyzed by Cation Exchange Resin: Kinetic Insight. Journal of Chemistry and Technologies 2023, 31, 167-177. https://doi.org/10.15421/jchemtech.v31i1.267433
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[21] Melnyk, S.R.; Khlibkevych, U.I.; Melnyk, Yu.R.; Mahorivska, H.Ya. Kinetic Research and Modeling of Benzoic Acid Esterification Process. Journal of Chemistry and Technologies 2021, 29, 559-569. https://doi.org/10.15421/jchemtech.v29i4.241445
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