Antibiocorrosive Hybrid Materials with High Durability
Affiliation:
1Department of Medical Chemistry, Faculty of Pharmacy, Tbilisi Medical University,
33Vazha Pshavela Ave., Tbilisi 0186, Georgia
2 Institute of Inorganic-Organic Hybrid Compounds and Nontraditional Materials,
Faculty of Exact and Natural Sciences, Ivane Javahishvili University,
3 Ilia Chavchavadze Ave., Tbilisi 0179, Georgia
3Laboratory of Advanced Polymers & Optimized Materials (LAPOM),
Department of Materials Science and Engineering and Department of Physics,
University of North Texas,
3940 North Elm Street,Denton TX 76207, USA
4 College of Mechanics and Robotics, AGH University of Science and Technology,
30 Adama Mickiewicza Aleja, Krakow 30-059, Poland
wkbrostow@gmail.com
DOI:
https://doi.org/10.23939/chcht15.04.500
| Attachment | Size |
|---|---|
 full_text.pdf | 3.16 MB |
Abstract:
We have developed novel antibiocorrosive multifunctional hybrid materials based on functionalizedperfluoroalkylmethacrylate copolymerswith epoxy groups in main chainsand selected biologically active compounds.The hybrids are transparent, showgood adhesion to various surfaces (plastic, wood),high viscoelastic recovery in scratch testing,low wear rates and glass transitions above 323 K. No phase separation is seen in scanning electron micrography. Enhanced mechanical strength and good abrasion resistance are advantages for uses of our protective and antibiocorrosive coatings in various applications including protection of cultural heritage.
References:
[1] Sambhy V., MacBride M., Peterson B., Sen A.: J. Am. Chem. Soc., 2006, 128,9798.https://doi.org/10.1021/ja061442z
https://doi.org/10.1021/ja061442z
[2] Preserving our Heritage, Improving our Environment, European Commission, DG Research, Information and Communication Unit, Brussels2009.
[3] Gomez-RomeroP., SanchezC.: Functional Hybrid Materials, Wiley-VCH, Weinheim 2006.
[4] ChujoY., KONA Powder Part. J., 2007, 25, 255.https://doi.org/10.14356/kona.2007023
https://doi.org/10.14356/kona.2007023
[5] Zvonkina I., Soucek M.:Curr. Opin. Chem. Eng., 2016, 11, 123.https://doi.org/10.1016/j.coche.2016.01.008
https://doi.org/10.1016/j.coche.2016.01.008
[6] KenawyE., Worley S., BroughtonR.Biomacromolecules, 2007,8,1359.https://doi.org/10.1021/bm061150q
https://doi.org/10.1021/bm061150q
[7] Mammadova N., Abbasov V., Mammadkhanova S., Ahmadbayova S.Proc. Petrochem. Oil Ref. 2018, 19, 180.
[8] SavelyevYu.: Polyurethane Thermoplastic Elastomers Comprising Hydrazine Derivatives: Chemical Aspects [in:] FakirovS. (Ed.), Handbook of Condensation Thermoplastic Elastomers, Wiley-VCH, Weinheim 2005, 355-380. https://doi.org/10.1002/3527606610.ch13
https://doi.org/10.1002/3527606610.ch13
[9] VitaleA., BongiovanniR., Ameduri B.:Chem. Rev.,2015,115, 8835.https://doi.org/10.1021/acs.chemrev.5b00120
https://doi.org/10.1021/acs.chemrev.5b00120
[10] TengH.:Appl. Sci.,2012, 2, 496.https://doi.org/10.3390/app2020496
https://doi.org/10.3390/app2020496
[11] Kostov G., Ameduri B., Boutevin B.: J. Fluor. Chem., 2002,114, 171.https://doi.org/10.1016/S0022-1139(02)00023-4
https://doi.org/10.1016/S0022-1139(02)00023-4
[12] Lekishvili N., Lachinov M., Zaikov G.:Fluorine-containing Polymers for Materials with the Complete Internal Light-reflection (Review) [in:] Pethrick R, Zaikov G. (Eds.) Polymer Yearbook. Rapra technology 2003,209-250.
[13] ErolI., ArslanturkB., Gurler Z.:Polym.Sci. B, 2015, 3, 228.https://doi.org/10.1134/S1560090415030045
https://doi.org/10.1134/S1560090415030045
[14] Smith Jr. D., Iacono S., Boday D., Kettwick S.(Eds.):Advances in Fluorine-Containing Polymers.ACS Symposium Series Vol. 1106, 2013.
https://doi.org/10.1021/bk-2012-1106
[15] Mukbaniani O., Brostow W., Aneli J. et al.: Mater. Technol., 2020, 54, 33.https://doi.org/10.17222/mit.2019.091
https://doi.org/10.17222/mit.2019.091
[16] YaoW., Li Y., HuangX.:Polymer, 2014, 55, 6197.https://doi.org/10.1016/j.polymer.2014.09.036
https://doi.org/10.1016/j.polymer.2014.09.036
[17] LekishviliN., NadareishviliL., Zaikov G., Khananashvili L.: Polymers and Polymeric Materials for Fiber and Gradient Optics. VSP (International Science Publi¬shers), Utrecht-Boston-Köln-Tokyo 2002.
[18] BarbakadzeKh., BrostowW., DatashviliT.et al.:Wear, 2018, 394-395, 228.https://doi.org/10.1016/j.wear.2017.08.006
https://doi.org/10.1016/j.wear.2017.08.006
[19] BarbakadzeKh., BrostowW., HnatchukN.et al.:Mater. Res. Innovat., 2015,19, 227.https://doi.org/10.1179/1433075X14Y.0000000256
https://doi.org/10.1179/1433075X14Y.0000000256
[20] Lachinov M., Guliashvili T., Lekishvili N., Khananashvili L.: Polym. Sci. A, 1998, 40, 88.
[21] LekishviliN.,BarbakadzeKh., ZurabishviliD.et al.:Oxid. Commun., 2010, 33, 104.
[22] Sadym A., Lagunin A., Filimonov D., Poroikov V.: Chem. Pharm. J., 2002, 36, 21.https://doi.org/10.1023/A:1022402425883
https://doi.org/10.1023/A:1022402425883
[23] Menard K.P.: Ch. 6 [in:] Brostow W.(Ed.), Performance of Plastics. Hanser, Munich -Cincinnati 2000.
[24] Khedkar J., Negulescu I., Meletis E.: Wear,2002, 252, 361.https://doi.org/10.1016/S0043-1648(01)00859-6
https://doi.org/10.1016/S0043-1648(01)00859-6
[25]Brostow W., Hagg Lobland H.: Materials: Introduction and Applications, John Wiley & Sons, 2017.
[26] Kalogeras I.,HaggLobland H.:J. Mater. Educ., 2012, 34, 69.
[27] BrostowW., Hagg Lobland H., Narkis M.: J. Mater. Res., 2006, 21, 2422.https://doi.org/10.1557/jmr.2006.0300
https://doi.org/10.1557/jmr.2006.0300
[28] BrostowW., KumarP., Vrsaljko D., Whitworth J.: J. Nanosci. Nanotech., 2011, 11, 3922.https://doi.org/10.1166/jnn.2011.3849
https://doi.org/10.1166/jnn.2011.3849
[29] TravinskaiaT., MishukE., PerepelitisinaL.,SavyelyevYu.: Polimernyi Zh., 2010, 32, 66.
[30] BardellaF., Montes RodriguesA., Leal Neto R., Crystalwalk: J. Mater. Educ., 2019, 41, 157.
[31] Zhang Y.: J. Mater. Educ., 2019, 41, 51.
[32] KrzywickaM., GrudzinskiJ., CzarnackaK.: J. Mater. Educ., 2020, 42, 245.
[33] ÇomezN., GülC., DurmusH., Sadrettin ZeybecM.: J. Mater. Educ., 2020, 42, 235.
[34] Fedotov A., Drozdov N., Mazanik A. et al.: J. Mater. Educ., 2007, 29, 35.
[35] MiddeaA., MonteM., Lucas E.: Chem. Chem. Technol., 2008, 2, 91. https://doi.org/10.23939/chcht02.02.091
https://doi.org/10.23939/chcht02.02.091
[36] Garretto M., GonzalezG., RamosA., Lucas E.: Chem. Chem. Technol., 2010, 4, 317.https://doi.org/10.23939/chcht04.04.317
https://doi.org/10.23939/chcht04.04.317
[37] SpinelliL., Lucas E.: J. Mater. Educ., 2017, 39, 125.
[38] Vianna E., Figuiredo V., Middea A. et al.: J. Mater. Educ., 2019, 41, 41.
[39] Guerrero-Martin C., Montes-Paéz E., Lucas E.: J. Mater. Educ.,2019, 41, 189.
[40] Gedde U., Hedenqvist M.: Fundamental Polymer Science, 2nd edn. Springer Nature, Switzerland 2019. https://doi.org/10.1007/978-3-030-29794-7
https://doi.org/10.1007/978-3-030-29794-7
[41]Grebowicz J., LauS.-F., Wunderlich B.:J. Polym. Sci., 1984, 71, 19. https://doi.org/10.1002/polc.5070710106
https://doi.org/10.1002/polc.5070710106
[42] TaczałaJ., Sawicki J., Pietrasik J.: Materials, 2020, 13, 3807.https://doi.org/10.3390/ma13173807
https://doi.org/10.3390/ma13173807
[43] BilyeuB., Brostow W., Menard K.P.:J. Mater. Educ., 1999, 21, 281.
[44] BilyeuB., Brostow W., Menard K.P.: J. Mater. Educ., 2000, 22, 107.
[45] BilyeuB., Brostow W., Menard K.P.: J. Mater. Educ., 2001, 23, 189
[46] BilyeuB., Brostow W., Menard K.P.:Polym. Compos., 2002, 23, 1111. https://doi.org/10.1002/pc.10505
https://doi.org/10.1002/pc.10505
[47] IatsyshynO., AstakhovaO., Shyshchak O.et al.:Chem. Chem. Technol., 2013, 7, 73.https://doi.org/10.23939/chcht07.01.073
https://doi.org/10.23939/chcht07.01.073
[48] BratychakM., AstakhovaO., ShyshchakO. et al., Chem. Chem. Technol., 2019, 13, 360.https://doi.org/10.23939/chcht13.03.360
https://doi.org/10.23939/chcht13.03.360
[49] BratychakM., AstakhovaO., ShyshchakO.et al.: Chem. Chem. Technol.,2020, 14, 343.https://doi.org/10.23939/chcht14.03.343
https://doi.org/10.23939/chcht14.03.343
[50] BratychakM., AstakhovaO., Shyshchak O.: Chem. Chem. Technol., 2020, 14, 504.https://doi.org/10.23939/chcht14.04.504
https://doi.org/10.23939/chcht14.04.504
Current Issues
The journal is accepted into Emerging Sources Citation Index (ESCI) - new index in the Web of Science™ Core Collection
The journal is indexed in the international scientometric databases:
