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Preparation of Secondary pH of Phthalate Buffer Solution Using Differential Potentiometric Cell: Method Validation and Application

Ayu Hindayani1, Oman Zuas1, , Sujarwo2, Fransiska S. H. Krismastuti2, Nuryatini1
Affiliation: 
1 Metrology in Chemistry Laboratory, Centre for Research and Human Resource Development, National Standardization Agency of Indonesia (BSN), Kawasan PUSPIPTEK Build. 420, Serpong15314, Tangerang Selatan-Banten, Indonesia 2 Research Centre for Chemistry-Indonesian Institute of Sciences (RCChem-LIPI) Kawasan PUSPIPTEK Build. 452, Serpong15314, Tangerang Selatan-Banten, Indonesia oman@bsn.go.id; zuas.oman@gmail.com
DOI: 
https://doi.org/10.23939/chcht13.03.377
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Keywords:

Abstract: 
A secondary pH of phthalate buffer was prepared by differential potentiometry method using a Baucke cell which is separated by sintered glass disk in the middle of cell – so called two-half cells. The method has been validated at 298 K with the purpose to evaluate its suitability for meeting the application requirement. The method validation parameters include accuracy (bias), precision (repeatability), and estimation of measurement uncertainty. It was found that both accuracy and precision of the method were good, which is indicated by their very low standard deviation (SD). The measurement uncertainty value of the method was estimated. Application of the validated analytical method for the measurement of phthalate buffer in an international comparative test (APMP.QM-K91) showed that the result was close to the APMP.QM-K91’s Key Comparison Reference Value.
References: 

[1] Buck R., Rondinini S. et al.: Pure Appl. Chem. 2002, 74, 2169. https://doi.org/10.1351/pac200274112169
[2] Gonzaga F., Dias J., Jehnert D. et al.: Electroanal., 2013, 25, 1955.
https://doi.org/10.1002/elan.201300135
[3] Laongsri B., Boonyakong C., Tangpaisarnkul N., Cherdchu C.: Accred. Qual. Assur., 2017, 12, 194.
https://doi.org/10.1007/s00769-006-0210-0
[4] Wu Y., Koch W., Marinenko G.: J. Res. Nat. Bur. Stand., 1984, 89, 395.
[5] European Pharmacopoeia, 4th edn. Council of Europe, Strasbourg 2002.
[6] Spitzer P., Pratt K.: J. Solid State Electrochem., 2011, 15, 69. https://doi.org/10.1007/s10008-010-1106-9
[7] Nuryatini, Sujarwo, Hindayani A.: J. Standardisasi, 2015, 18, 35.
[8] Hetzer H., Durst R.: J. Res. Nat. Bur. Stand., 1977, 81A, 21.
[9] Magnusson B., Örnemark U. (Eds.): Eurachem Guide: The Fitness for Purpose of Analytical Methods – A Laboratory Guide to Method Validation and Related Topics, 2nd edn., 2014. www.eurachem.org.
[10] Gonzalez C., Watters Jr. R.: Certificate of Analysis SRM®NIST 185i Potassium Hydrogen Phthalate pH Standard, Department of Commerce United States of America 2013.
[11] Yildirim A.: Certificate of Analysis Certipure® Certified Reference Material Potassium Hydrogen Phthalate, MERCK, Germany 2015.
[12] Baucke F.: J. Electroanal. Chem., 1994, 368, 67. https://doi.org/10.1016/0022-0728(93)03024-J
[13] Mustopo Y.: Effect of Time on Thickness and Adhesivity Layer in Electroplating Process of Chrome Decorative without Basic Layer with Copper Basic Layer and Copper-Nickel., Department of Mechanical Engineering, Technical Faculty of UNS, Solo, Indonesia 2011.
[14] Hamer W., Acree S.: J. Res. Nat. Bur. Stand., 1944, 33, 87.
[15] Budiman H.: Warta Kimia Analitik., 2014, 20, 18.
[16] Bell S.: Measurement Good Practice Guide (Issue 2), National Physical Laboratory, United Kingdom 2001.
[17] Subangga B., Sutikno E., Ariseno A.: Effect of Anode Variation and time of Electroplating on Wear Rate of Grinding Ball., Department of Mechanical Engineering University of Brawijaya Malang.
[18] Hioki A., Asakai T., Maksimov I. et.al.: Metrologia, 2017, 54, 08002. https://doi.org/10.1088/0026-1394/54/1A/08002