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Interpenetrating Network on the Basis of Methylcyclotetrasiloxane Matrix

Omari Mukbaniani1, 2, Jimsher Aneli2, Marta Plonska-Brzezinska3, Eliza Markarashvili1, 2, Tamar Tatrishvili1, 2
Affiliation: 
1 Iv. Javakhishvili Tbilisi State University, 1, I. Chavchavadze Ave., 0179 Tbilisi, Georgia 2 Institute of Macromolecular Chemistry and Polymeric Materials, Iv. Javakhishvili Tbilisi State University, 13, I. Chavchavadze Ave., 0179 Tbilisi, Georgia 3 Faculty of Biology and Chemistry, University of Bialystok, Ciolkowskiego 1K,15-245 Bialystok, Poland omar.mukbaniani@tsu.ge
DOI: 
https://doi.org/10.23939/chcht13.01.064
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Keywords:

Abstract: 
Hydrosilylation reaction of 2,4,6,8-tetrahydro-2,4,6,8-tetramethylcyclotetra siloxane (D4H) allyl trifluoroacetate and vinyltriethoxysilane catalysed by platinum catalysts has been studied.The synthesized D4R,R' was analyzed with FTIR, 1H, 13C, and 29Si NMR spectroscopy. Via sol-gel reactions of D4R,R' systems doped with lithium trifluoromethylsulfonate (triflate) solid polymer electrolyte membranes have been obtained. It has been found that the electric conductivity of the polymer electrolyte membranes at room temperature changes in the range of (4•10-5)–(6•10-7) S/cm.
References: 

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