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The Acid-Base Interaction Role in the Processes of the Filled Diane Epoxy Resins Structuring

Yuliya Danchenko, Mariya Kachomanova, Yelena Barabash
Affiliation: 
1 Kharkiv National University of Civil Engineering and Architecture, 40 Sumska St., 61002 Kharkiv, Ukraine u_danchenko@ukr.net
DOI: 
https://doi.org/10.23939/chcht12.02.188
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PDF icon full_text.pdf2.42 MB

Keywords:

Abstract: 
The processes of the ED-20 diane epoxy resin structuring, containing disperse oxidic fillers and modifiers are studied with the help of the rotational viscometry method. It is shown that the acid -base interactions between the functional groups of the resin part molecules and the active centers of the fillers surface play the defining role in these processes. The structure degree is defined both by the total amount of the surface active centers, and their pKa value. It is approved that the diffusive phenomena intensity is defined by the acid force of the fillers hydroxyl groups whereas the share of the volume effects in the compositions is small.
References: 

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