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Catalytic Oxidation of Cyclohex-2-enol at Porous Iron Zeolite-like Material: Investigations by GC/MS, Polarography and X-ray Powder Diffraction

Khalid Hamad Abu-Shandi
Affiliation: 
1 Department of Chemistry, Faculty of Science, Technical Tafila University, P. O. Box 179, Tafila 66110-Jordan. khalidshandi@yahoo.com
DOI: 
https://doi.org/10.23939/chcht12.02.147
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Keywords:

Abstract: 
The polymeric complexes of porous iron phosphates (NH4)4Fe3II(OH)2F2[H3(PO4)4] (1), (C3H12N2)FeII6(H2O)4[B4P8O32(OH)8] (2), and {[FeII(H2PO4)2-(μ-4,4'-bipy)(H2O)]•H2O•(4,4'-bipy)} (3) were successfully tested towards oxidation of cyclohex-2-enol. The resulting products have been monitored and characterized using gas chromatography/mass spectroscopy, IR spectroscopy, and elemental analysis. Structural properties of the polymeric complexes have been studied using powder X-ray diffraction and electrochemical measurements. The results indicate that these complexes display an irreversible redox process and have high thermal stability. The results also indicated that these complexes undergo a phase change as evidenced by the change of the state of oxidation of metal centres.
References: 

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