Formation of Excited Molecules from Fragments Formed in Heterogeneous-Homogeneous Processes in the Near-Surface Layer and Their Impact on Oxidation Processes

Garnik Sargsyan1, Naira Baghdasaryan2, Hrachya Sargsyan3, Yurii Klimko4

Affiliation:

1 Institute of Chemical Physics after A.B. Nalbandyan of the National Academy of Sciences of the Republic of Armenia, Hydrocarbon Oxidation Laboratory, 5/2 Paruir Sevak St., Yerevan 0014, Armenia 2 Erebuni Medical Academy Foundation, Preclinical Department, 133 Titogradian St., Yerevan 0087, Armenia 3 Institute of Chemical Physics after A.B. Nalbandyan of the National Academy of Sciences of the Republic of Armenia, Laboratory of Liquid Phase Free-Radical Reactions, 5/2 Paruir Sevak St., Yerevan 0014, Armenia 4 National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Department of Organic Chemistry and Technology of Organic Compounds, 37 Beresteiskyi Ave., Kyiv 03056, Ukraine sar.garnik41@gmail.com

DOI:

https://doi.org/10.23939/chcht19.03.463

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Keywords:

shock waves; Hugoniot theory; resonance; relaxation; ion-molecular reactions

Abstract:

This study focuses on the formation of excited molecules and their significant role in influencing dynamic regimes of low-temperature oxidation, particularly in the context of methane and acetaldehyde reactions. The investigation reveals how quantum resonance facilitates the formation of excited formaldehyde molecules, driving energy transfer processes that influence radical chain reactions and inhibit oxidation. These processes lead to the formation of weak shock waves, which emerge due to the interaction of water complexes with negative halogen ions and the self-decomposition of ozone. Using theoretical modeling, computer simulations, and spectroscopy, the study uncovers the role of quantum resonance in generating weak shock waves and establishing oscillatory regimes. These findings contribute to a deeper understanding of the mechanisms of low-temperature oxidation and the complex interactions of excited molecules, offering new applications in both scientific research and industry.

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Formation of Excited Molecules from Fragments Formed in Heterogeneous-Homogeneous Processes in the Near-Surface Layer and Their Impact on Oxidation Processes

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