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Features of the calculation of the liquidus temperature of sodium borosilicate glasses in the presence of Fe2O3 and Cr2O3

Serhii Matsenko1, Olga Ryzhova1, Oleksii Sihunov1
Affiliation: 
1 Department of chemical technologies of ceramics, glass and biomedical materials. Ukrainian State University of Science and Technologies, 2, Lazariana St., Dnipro 49010, Ukraine sermats.dcb@gmail.com
DOI: 
https://doi.org/
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Keywords:

Abstract: 
This paper discusses the application of Kauzmann’s rule for calculating the liquidus temperature of glasses in the Na₂O–B₂O₃–SiO₂ system. The dependence of the adjusted glass transition temperature (Tgr) on the structure of sodium borosilicate glass is established, and the influence of Fe₂O₃ and Cr₂O₃ additives on this parameter is investigated. For compositions prone to crystallization and aventurine formation, a regression equation is calculated to describe the dependence of Tgr on the chemical composition of the glasses. Additionally, a methodology for applying Kauzmann’s rule to calculate the liquidus temperature of oxide glasses, considering the dilatometrically determined glass transition temperature (Tg), is proposed for the studied compositions. This allows the calculation of the liquidus temperature without the need for differential thermal analysis.
References: 

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