Synthesis of Copolymer from 1,3,5-Trioxane and -Caprolactone Catalysed by Treated Bentonite as Eco-Catalyst
Affiliation:
1 Laboratory of Polymer Chemistry, Department of Chemistry, Faculty of Exact and Applied Sciences, University Oran 1, Ahmed Ben Bella, BP N°1524 EL M’Naouer, 31000, Oran, Algeria.
benmoussa.hanane@edu.univ-oran1.dz,
mohammed.ferrahi@yahoo.fr
DOI:
https://doi.org/10.23939/chcht17.01.081
| Attachment | Size |
|---|---|
 full_text.pdf | 447.95 KB |
Abstract:
This study presents a novel green method for copolymerizing 1,3,5-trioxane (TOX) with ε caprolactone (CL). This technique uses Maghnite-H+ (Mag-H+) as a bulk green catalyst. Various techniques were used to confirm the structure of the resulting copolymer. The influencing factors on the copolymerization reaction were also studied. The results show that the best copolymer yield (46.3 %) was obtained via bulk copolymerization at a temperature of 353 K for a reaction time of 8 h.
References:
[1] Schweitzer, C.E.; Macdonald, R.N.; Punderson, J.O. Thermally Stable High Molecular Weight Polyoxymethylenes. J. Appl. Polym. Sci. 1959, 1, 158-163. https://doi.org/10.1002/app.1959.070010205
https://doi.org/10.1002/app.1959.070010205
[2] Matsuzaki, K.; Hata, T.; Sone, T.; Masamoto, J. New Polyacetal Process from Formaldehyde Polymerization in the Presence of a Chain Transfer Agent. Bull. Chem. Soc. Jpn. 1994, 67, 2560-2566. https://doi.org/10.1246/bcsj.67.2560
https://doi.org/10.1246/bcsj.67.2560
[3] Yamasaki, N.; Kanaori, K.; Masamoto, J. Analysis of Ethylene Oxide Sequences of the Acetal Copolymer from Trioxane and Ethylene Oxide. J. Polym. Sci. A Polym. Chem. 2001, 39, 3239-3245. http://dx.doi.org/10.1002/pola.1306
https://doi.org/10.1002/pola.1306
[4] Yamasaki, N.; Masamoto, J. Novel Reaction between Cyclic Formal and Ethylene Oxide. J. Polym. Sci. A Polym. Chem. 2004, 42, 520-533. https://doi.org/10.1002/pola.10861
https://doi.org/10.1002/pola.10861
[5] Belbachir, M.; Bensaoula, A. Composition and Method for Catalysis Using Bentonite. US 7094823 B2, 2006.
[6] Belmokhtar, A.; Sahli, N.; Yahiaoui, A.; Belbachir, M.
Polycondensation of Pyrrole and Benzaldehyde Catalyzed by Ma-ghnite-H+. Express Polym. Lett. 2007, 7, 443-449. https://doi.org/10.3144/expresspolymlett.2007.62
https://doi.org/10.3144/expresspolymlett.2007.62
[7] Mekki, H.; Belbachir, M. Preparation of Vinyl Chloride - Vinyl Ether Copolymers via Partial Etherification from PVC. Express Polym. Lett. 2007, 1, 495-498. https://doi.org/10.3144/expresspolymlett.2007.70
https://doi.org/10.3144/expresspolymlett.2007.70
[8] Yahiaoui, A.; Hachemaoui, A.; Belbachir, M. Synthesis of Hydrosoluble Polymers of Oxazoline Using Maghnite-H as Catalyst. J. Appl. Polym. Sci. 2007, 104, 1792-1800. https://doi.org/10.1002/app.25829
https://doi.org/10.1002/app.25829
[9] Harrane, A.; Meghabar, R.; Belbachir, M. A Protons Exchanged Montmorillonite Clay as an Efficient Catalyst for the Reaction of Isobutylene Polymerization. Int. J. Mol. Sci. 2002, 3, 790-800. https://doi.org/10.3390/i3070790
https://doi.org/10.3390/i3070790
[10] Bennabi, S.; Sahli, N.; Belbachir, M.; Brachais, C.-H.; Boni, G.; Couvercelle, J.-P. A New Approach for the Synthesis of Poly(ethylglyoxylate) Using Mag-H+, an Algerian Proton Exchanged Montmorillonite Clay, as an Eco-Catalyst. J. Macromol. Sci. A 2017, 54, 843-852. https://doi.org/10.1080/10601325.2017.1339558
https://doi.org/10.1080/10601325.2017.1339558
[11] Derdar, H.; Belbachir, M.; Harrane, A. A Green Synthesis of Polylimonene Using Mag-H+, an Exchanged Montmorillonite Clay, as Eco-Catalyst. Bull. Chem. React. Eng. Catal. 2019, 14, 69-78. https://doi.org/10.9767/bcrec.14.1.2692.69-78
https://doi.org/10.9767/bcrec.14.1.2692.69-78
[12] Reguieg, F.; Sahli, N.; Belbachir, M. Nanocomposite Hydrogels Based on Water Soluble Polymer and Montmorillonite-Na+. Orient. J. Chem. 2015, 31, 1645-1657. http://dx.doi.org/10.13005/ojc/310343
https://doi.org/10.13005/ojc/310343
[13] Reguieg, F.; Sahli, N.; Belbachir, M.; Lutz, P.J. One-Step Synthesis of Bis‐Macromonomers of Poly(1,3-dioxolane) Catalyzed by Maghnite‐H+. J. Appl. Polym. Sci. 2006, 99, 3147-3152. https://doi.org/10.1002/app.22935
https://doi.org/10.1002/app.22935
[14] Belbachir, M.; Bensaoula, A. Composition and Method for Catalysis Using Bentonites. US 0069446 A1, 2003.
[15] Derdar, H.; Belbachir, M.; Hennaoui F.; Akeb, M.; Harranem, A. Green Copolymerization of Limonene with β-Pinene Catalyzed by an Eco-Catalyst Maghnite-H+. Polym. Sci. Ser. B+ 2018, 60, 555-562. https://doi.org/10.1134/S1560090418050056
https://doi.org/10.1134/S1560090418050056
[16] Górniak, K.; Szydłak, T.; Gaweł, A.; Klimek, A.; Tomczyk, A.; Motyka, J.; Bahranowski, K. Smectite-, Silica- and Zeolites-Bearing Raw Materials (Hliník nad Hronom bentonite, Slovakia) - A New Approach Using Integrated Petrographic and Mineralogical Studies. Appl. Clay Sci. 2017, 141, 180-191. https://doi.org/10.1016/j.clay.2017.02.032
https://doi.org/10.1016/j.clay.2017.02.032
[17] Beloufa, K.; Sahli, N.; Belbachir, M. Synthesis of Copolymer from 1,3,5‐Trioxane and 1,3‐Dioxolane Catalyzed by Maghnite‐H+. J. Appl. Polym. Sci. 2010, 115, 2820-2827. https://doi.org/10.1002/app.30901
https://doi.org/10.1002/app.30901
[18] Lam, K.L.; Abu Bakar, A.; Ishak, Z.A.M.; Karger-Kocsis, J. Amorphous Copolyester/Polyoxymethylene Blends: Thermal,
Mechanical and Morphological Properties. Kautschuk Gummi Kunststoffe 2004, 57, 570-578.
[19] Mu, Y.; Jia, M.; Jiang, W.; Wan, X. A Novel Branched Poly-oxymethylene Synthesized by Cationic Copolymerization of 1,3,5-Trioxane with 3-(Alkoxymethyl)-3-ethyloxetane. Macromol. Chem. Phys. 2013, 214, 2752-2760. https://doi.org/10.1002/macp.201300473
https://doi.org/10.1002/macp.201300473
[20] Belbachir, M.; Bensaoula, A. Composition and Method for Catalysis Using Bentonites. US 6274527 B1, 2001.
Current Issues
The journal is accepted into Emerging Sources Citation Index (ESCI) - new index in the Web of Science™ Core Collection
The journal is indexed in the international scientometric databases:
