Synthesis and Characterization of Fluorene-Imidazole Copolymers
Affiliation:
1 Department of Chemistry Education, Kyungpook National University,
Daegu 702-701, Korea; ddk-odw@daum.net
2 Department of Nano Engineering, Sangju Campus, Kyungpook National University,
Sang Ju 742-711, Korea
DOI:
https://doi.org/10.23939/chcht07.04.405
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Abstract:
New PAF derivatives [poly(fluorene-co-1,3-diphenylimidazolium chloride) 7 and poly(fluorene-co-1,3-diphenylimidazol-2-thione) 9] with high thermal stability were synthesized and their physical and optical properties were investigated. The obtained polymers were characterized by 1H NMR, 13C NMR, DSC, TGA, GPC, and SEM-EDX. Thermogravimetric analysis (TGA) showed excellent thermal stability of the resulting polymers. Initial weight loss (5 %) was observed around 700 K, with the main decomposition occurring around 760 K (50 %). The glass transition temperature of 9 was higher than that of the host copolymer 7. The copolymers in this study emitted in the blue region with a maximum around 440 nm. The emission spectra of copolymer 9 showed a red shift compared to that of the host copolymer 7. The optical band gaps deduced from the onset of the absorption of copolymers were about 3.06 and 2.91 eV for copolymers 7 and 9, respectively.
References:
[1] Ranger M. and Leclerc M.: Chem. Commun., 1997, 1597.
https://doi.org/10.1039/a703076b
[2] Setayesh S., Marsitzky D. and Mullen K.: Macromolecules, 2000, 33, 2016.
https://doi.org/10.1021/ma9914366
[3] Setayesh S., Grimsdale A., Weil. T. et al.: J. Am. Chem. Soc., 2001, 123, 946.
https://doi.org/10.1021/ja0031220
[4] Lee J., Klaerner G. and Miller R.: Chem. Mater., 1999, 11, 1083.
https://doi.org/10.1021/cm981049v
[5] Ranger M., Rondeau D. and Leclerc M.: Macromolecules, 1997, 30, 7686.
https://doi.org/10.1021/ma970920a
[6] Fukuda M., Sawada K. and Yoshino K.: J. Polym. Sci. A, 1993, 31, 2465.
https://doi.org/10.1002/pola.1993.080311006
[7] Chou C. and Shu C.: Macromolecules, 2002, 35, 9673.
https://doi.org/10.1021/ma0210271
[8] Renqiang Y., Renyu T., Jingai Y. et al: Macromolecules, 2005, 38, 244.
https://doi.org/10.1021/ma047969i
[9] Oh D., Lee W. and Park J.: Chem. & Chem. Techn., 2013, 7, 47.
https://doi.org/10.23939/chcht07.01.047
[10] Murray R., Trozzolo A., Wasserman E. and Yager W.: J. Am. Chem. Soc., 1962, 84, 3213.
https://doi.org/10.1021/ja00875a054
[11] Arduengo A. and Wilmington D.: Pat US 5077414, Publ. Dec. 31, 1991.
[12] Arduengo A., Harlow R., Kline M. and Dias H.: J. Am. Chem. Soc.,1992, 114, 5530.
https://doi.org/10.1021/ja00040a007
[13] Dixon D. and Arduengo A.: J. Phys. Chem., 1991, 95, 4180.
https://doi.org/10.1021/j100164a003
[14] Huang J., Stevens E., Nolan S. and Petersen J.: J. Am. Chem. Soc., 1999, 121, 2674.
https://doi.org/10.1021/ja9831352
[15] Downing S., Guadano S., Pugh D. et al.: Organometallics., 2007, 26, 3762.
https://doi.org/10.1021/om700269u
[16] Arduengo A.: Acc. Chem. Res., 1999, 32, 913.
https://doi.org/10.1021/ar980126p
[17] Herrmann W. and Kocher C.: Angew. Chem. Int. Ed. Engl., 1997, 36, 2162.
https://doi.org/10.1002/anie.199721621
[18] Lorber C. and Vendier L.: Organometallics., 2008, 27, 2774.
https://doi.org/10.1021/om800121g
[19] Kuhn N., Kratz T., Blaer D. and Boese R.: Inorganica Chimica Acta., 1995, 238, 179.
https://doi.org/10.1016/0020-1693(95)04701-A
[20] Arduengo A. and Wilmington D.: Pat US 5162482, Publ. Nov. 10, 1992.
[21] Regitz M.: Angew. Chem., 1991, 103, 691.
https://doi.org/10.1002/ange.19911030609
[22] Kuhn N., Kratz T., Blaser D. and Boese R.: Chem. Ber., 1995, 128, 245.
https://doi.org/10.1002/cber.19951280307
[23] Jianfeng L., Carola S., Sebastian M. et al.: Z. Anorg. Allg. Chem., 2010, 636, 511.
https://doi.org/10.1002/zaac.200900486
[24] Benac B., Burgess E. and Arduengo A.: Org. Synth., 1986, 64, 92.
https://doi.org/10.15227/orgsyn.064.0092
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