Spectrophotometric Determination of Ruthenium Utilizing its Catalytic Activity on Oxidation of Hexacyanoferrate(II) by Periodate Ion in Water Samples

Abhishek Srivastava1, Vivek Sharma1, Anjali Prajapati1, Neetu Srivastava2, R.M. Naik3
Affiliation: 
1 Department of Chemistry, G.L.A. University, Mathura, U.P., India 2 Department of Chemistry, D.D.U. Gorakhpur University, Gorakhpur, 273001, U.P., India 3 Department of Chemistry, Lucknow University, Lucknow, 226001, U.P. India  aabhichem@gla.ac.in
DOI: 
https://doi.org/10.23939/chcht13.03.275
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Abstract: 
The catalytic effect of ruthenium chloride on the outer sphere electron transfer of hexacyanoferrate(II) by periodate ion in aqueous alkaline medium has been effectively employed to determine ruthenium(III) at micro level. The optimum reaction condition has been established and fixed time procedure is adopted. A linear relationship between changes in absorbance and added Ru(III) concentration has been utilized for the trace level determination of Ru(III). The results reveal that the addition of interfering ions (up to 71 times higher concentration of Ru) does not have significant effect on the catalytic activity of Ru(III) on oxidation of hexacyanoferrate(II) by periodate ion. Polyaminocarboxylates (HEDTA, EDTA and IDA) suppress its catalytic power to maximum, if tolerance limit is more than 14.29 times. Due to the reproducibility, stability and selectivity, this method can also be quantitatively applied in different types of water samples for determination of ruthenium(III) at micro level.
References: 

[1] Balcerzak M.: Rev. Anal. Chem., 2002, 32, 181. https://doi.org/10.1080/10408340290765524
https://doi.org/10.1080/10408340290765524

[2] Druskovic V., Vojkovic V., Jelic T.: Croatica Chem. Acta, 2005, 78, 617.

[3] Berggren K., Steinberg T., Lauber W. et al.: Anal. Biochem., 1999, 276, 129. https://doi.org/10.1006/abio.1999.4364
https://doi.org/10.1006/abio.1999.4364

[4] Lindino C., Bulhoes L.: J. Braz. Chem. Soc., 2004, 15, 178. https://doi.org/10.1590/S0103-50532004000200004
https://doi.org/10.1590/S0103-50532004000200004

[5] Alarfa N., El-Razeq S.: J. Pharm. Biomed. Anal., 2006, 41, 1423. https://doi.org/10.1016/j.jpba.2006.03.011
https://doi.org/10.1016/j.jpba.2006.03.011

[6] Zhou Z., Zhang I.: Adv. Mater. Res., 2013, 602-604, 1289. https://doi.org/10.4028/www.scientific.net/AMR.602-604.1289
https://doi.org/10.4028/www.scientific.net/AMR.602-604.1289

[7] Zhou Z., Zhang I.: Appl. Mechanics Mater., 2012, 217-219, 2397. https://doi.org/10.4028/www.scientific.net/AMM.217-219.2397
https://doi.org/10.4028/www.scientific.net/AMM.217-219.2397

[8] Byadagi K., Nandibewoor S., Chimatadar S.: Acta Chim. Slov., 2013, 60, 617.

[9] Sharanabasamma K., Angadi A., Tuwar S.: The Open Catal. J., 2011, 4, 1. https://doi.org/10.2174/1876214X01104010001
https://doi.org/10.2174/1876214X01104010001

[10] Keyvanfard M.: World Acad. Sci. Eng. Tech. 2008, 43.

[11] Hosamani R., Nandibewoor S.: J. Chem. Sci., 2009, 121, 275. https://doi.org/10.1007/s12039-009-0030-y
https://doi.org/10.1007/s12039-009-0030-y

[12] Srivastava S., Chaudhary L., Singh K.: Int. J. Res. in Phys. Chem., 2012, 2, 6.

[13] Babasaheb D., Bhosale A., Gokavib G.: Adv. Appl. Sci. Res. 2012, 3, 785.

[14] Mishra K., Chaturvedi R., Shukla M.: Ind. J. Chem. 2010, 49A, 185.

[15] Kumar A., Reddy P., Reddy V.: Int. J. ChemTech. Res., 2013, 5, 1442.
https://doi.org/10.1155/2013/808764

[16] Ritika M., Barhate V.: Int. J. ChemTech. Res., 2013, 5, 1578.

[17] Sateesh B., Shastry V., Shashidhar S., Manoj K.: Int. J. Chem. Sci., 2014, 14, 1109.

[18] Fawaz A.: J. Chem. Sci., 2016, 128, 733. https://doi.org/10.1007/s12039-016-1067-3
https://doi.org/10.1007/s12039-016-1067-3

[19] Gorakh S., Antonio D., Jyoti G. et al.: Chem. Commun., 2013, 49, 11533. https://doi.org/10.1039/c3cc46239k
https://doi.org/10.1039/c3cc46239k

[20] Lakomska I., Fandzloch M., Muziol T. et al.: Dalton Trans., 2013, 42, 6219. https://doi.org/10.1039/c2dt32216a
https://doi.org/10.1039/c2dt32216a

[21] Sharma A., Gangrade, Bakshi D., John J.: Int. J. ChemTech. Res., 2014, 4, 828.

[22] Schoekel A., Melke J., Burns M. et al.: J. Power Sources, 2016, 301, 210. https://doi.org/10.1016/j.jpowsour.2015.09.119
https://doi.org/10.1016/j.jpowsour.2015.09.119

[23] Hsieh Y., Zang Y., Su D. et al.: Nat. Commun., 2013, 2466. https://doi.org/10.1038/ncomms3466
https://doi.org/10.1038/ncomms3466

[24] Messori L., Camarri M., Ferraro T. et al.: A.C.S. Med. Chem. Lett., 2013, 4, 1124. https://doi.org/10.1021/ml400390c
https://doi.org/10.1021/ml400390c

[25] Brunken S., Kratzig A., Bogdanoff P. et al.: Thin Solid Films, 2013, 527, 16. https://doi.org/10.1016/j.tsf.2012.12.037
https://doi.org/10.1016/j.tsf.2012.12.037

[26] Madan P., Barhate V.: Int. J. Sci. Res., 2016, 5, 778.

[27] Shelar S., Bhor R., Anuse M., Naval R.: Sep. Sci. Tech., 2015, 50, 1190. https://doi.org/10.1080/01496395.2014.983245
https://doi.org/10.1080/01496395.2014.983245

[28] Prasad S., Naik R., Srivastava A.: Spectrochim. Acta A, 2008, 69, 193. https://doi.org/10.1016/j.saa.2007.03.030
https://doi.org/10.1016/j.saa.2007.03.030

[29] Naik R., Srivastava A., Prasad S.: Spectrochim. Acta A, 2008, 70, 958. https://doi.org/10.1016/j.saa.2007.10.011
https://doi.org/10.1016/j.saa.2007.10.011

[30] Zhou Z., Zhang L.: Appl. Mech. Mater., 2012, 204-208, 4067.
https://doi.org/10.4028/www.scientific.net/AMM.204-208.4067

[31] Sreekanth B., Jonnalagadda, Brijesh P.: Anal. Lett., 2011, 1868.

[32] Jonnalagadda S., Chinake C., Love I.: Fresenius Anal. Chem., 1994, 349, 829. https://doi.org/10.1007/BF00323114
https://doi.org/10.1007/BF00323114

[33] Keyvanfard M., Rezaei B.: Can. J. Anal. Sci. Spectrosc., 2005, 50, 221.

[34] Crouch S., Scheeline A., Kirkor E.: Anal. Chem., 2000, 72, 53. https://doi.org/10.1021/a1000004b
https://doi.org/10.1021/a1000004b

[35] Prasad S.: Asian J. Chem., 2002, 14, 799.

[36] Prasad K., Rao N.: React. Kinet. Catal. Lett., 1995, 56, 273. https://doi.org/10.1007/BF02076032
https://doi.org/10.1007/BF02076032

[37] Khayamian T., Ensafi A., Atabati M.: Anal. Lett., 2002, 35, 2039. https://doi.org/10.1081/AL-120014292
https://doi.org/10.1081/AL-120014292

[38] Bhagwat V., Vijay R., Jonnalagadda S., Pare B.: Indian J. Chem. Technol., 2006, 13, 644.

[39] Naik R., Srivastava A., Asthana A.: J. Iran. Chem. Soc., 2008, 5, 29. https://doi.org/10.1007/BF03245812
https://doi.org/10.1007/BF03245812