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The Role of Oxides in Oxidation of Allyl Alcohol and its Esters

Eugeniy Fedevych1, Oleh Datsko2, Oleh Fedevych3
Affiliation: 
1 Lviv National Agrarian University, 1, V.Velykogo St., 80381 Dubliany, Lviv region, Ukraine 2 Bogomolets Institute of Physiology, Laboratory of Experimental Balneology, Truskavets, Ukraine 3 Lviv Polytechnic National University, 12, S.Bandery St., 79013 Lviv, Ukraine foe69@ukr.net
DOI: 
https://doi.org/10.23939/chcht13.01.046
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Keywords:

Abstract: 
The assumption that oxides (glycidol, glycidol acetate, glycidol formate) are the intermediate molecular products of the oxidation reaction of allyl alcohol and its esters in the medium of acetic acid has been grounded. To optimize the process of obtaining glycerin esters the kinetics of these oxides reaction with acetic and formic acids has been investigated. Glycidol formate was found to be the most stable compound and glycidol – the least stable one. The rate of oxides reaction with formic acid is by order higher than that with acetic acid. It is reasonable to use allyl formate as the starting material to achieve the maximum yields of glycerin esters.
References: 

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