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Properties of the Composites Made of Glauconite and Polyaniline in Aqueous Solutions of Phosphoric Acid

Solomiia Nesterivska1, Victoriia Makogon1, Мykhaylo Yatsyshyn1, Ivan Saldan1, Oleksandr Reshetnyak1, Nestor German1, Yurii Stadnyk1
Affiliation: 
1 Ivan Franko National University of Lviv, 6, Kyryla & Mefodiya St., 79005 Lviv, Ukraine mykhaylo.yatsyshyn@lnu.edu.ua
DOI: 
https://doi.org/10.23939/chcht14.04.487
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Keywords:

Abstract: 
The glauconite-polyaniline composites were prepared through oxidation of aniline using ammonium peroxodisulfate in aqueous solutions of phosphoric acid on the surface of a glauconite powder. Intermolecular interaction between amorphous polyaniline macromolecules and interphase coupling of polyaniline to the glauconite surface was confirmed by X-ray diffraction and FT-IR spectroscopy. Higher concentration of phosphoric acid led to a stronger intermolecular and interphase connection because of H-bonding, and that resulted in higher electric conductivity while a magnetic susceptibility of the composites was not affected. Thermal analysis for the prepared composites confirmed the interfacial interaction between the polyaniline macromolecules and the surface of powdered glauconite.
References: 

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