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Production of Bitumen Modified with Low-Molecular Organic Compounds from Petroleum Residues. 7. Study of the Structure of Formaldehyde Modified Tars

Volodymyr Gunka1, Yurii Hrynchuk1, Yuriy Demchuk1, Myroslava Donchenko1, Yuriy Prysiazhnyi1, Volodymyr Reutskyy1, Olena Astakhova1
Affiliation: 
1 Lviv Polytechnic National University, 12 S.Bandery St., 79013 Lviv, Ukraine volodymyr.m.hunka@lpnu.ua
DOI: 
https://doi.org/10.23939/chcht17.01.211
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Abstract: 
Three samples of bituminous material with different softening temperatures of 321, 332, and 356.4 K were obtained by the method of chemical modification of tar with formaldehyde using sulfuric acid as a catalyst. The determination of the group hydrocarbon composition was carried out for the raw materials of the modification process (tar) and the resulting bitumens. An FTIR study of the obtained groups of hydrocarbons (oil, resins, and asphaltenes) was also carried out. The structural transfor¬mations were investigated and a possible chemistry of the tar modification process with formaldehyde was proposed.
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