Preparation of Hierarchical ZSM-5 from Indonesian Kaolin by Adding Silica

Hartati Hartati, Alfa Widati, Harsasi Setyawati and Sarita Fitri
Department of Chemistry, Faculty of Science and Technology, Universitas Airlangga, Surabaya 60115, Indonesia;
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Hierarchical ZSM-5 was prepared using Bangka kaolin-Indonesia in the absence of structure directing agent. The effect of hydrothermal time and temperature was investigated. The prepared samples were characterized by XRD, XRF, FT-IR, and N2 adsorption/desorption. The results show that hierarchical ZSM-5 can be obtained at hydrothermal temperature of 393–448 K. Moreover, this method also produces mordenite and quartz as by-products.

[1] Perez-Ramırez J., Christensen C., Egeblad K. et al.: Chem. Soc. Rev., 2008, 37, 2530.

[2] Yang J., Yu S., Hu H. et al.: Chem. Eng. J., 2011, 166, 1083.

[3] Su B., Sanchez C., Yang X. et al.: Hirarkisly Structured Porous Materials: from Nanoscience to Catalysis, Wiley, Weinheim 2012.

[4] Na K., Choi M., Ryoo R. et al.: Micro. Meso. Mat., 2013, 166, 3.

[5] Shetti V., Kim J., Srivastava R. et al.: J. Catal., 2008, 254, 296.

[6] Schmidt F., Lohe M. and Büchner B.: Micro. Meso. Mat., 2013, 165, 148.

[7] Groen J., Bach T., Ziese U. et al.: J. Am. Chem. Soc., 2006, 127, 10792.

[8] Perez-Ramírez J., Verboekend D., Bonilla A. et al.: Adv. Funct. Mater., 2009, 19, 3972.

[9] Kim S., Noh H., Park J. et al.: Micro. Meso. Mat., 2006, 92, 181.

[10] Xiao Q., Yao Q., Zhuang J. et al.: J. Colloid Interf. Sci., 2013, 394, 604.

[11] Egeblad K., Christensen C., Kustiva M. et al.: Chem. Mater., 2008, 20, 946.

[12] Tao Y., Kanoh H., Abrams L. et al.: Chem. Rev., 2008, 108, 896.

[13] Vempati R., Borade R., Hegde R. et al.: Micro. Meso. Mat., 93, 134.

[14] Wang X., Xu H., Fu X. et al.: J. Mol. Catal. A, 2005, 238, 185.

[15] Prasetyoko D., Ayunanda N., Fansuri H. et al.: ITB J. Sci., 2012, 44A, 250.

[16] Murray H.: Applied Clay Mineralogy. Elsevier, Netherland 2007.

[17] Grim R.: Clay Mineralogy. Mcgraw-Hill, New York 1968.

[18] Adamis Z.: Bentonite, Kaolin and Selected Clay Minerals. World Health Organization, Geneva 2005.

[19] Liu B., Li C., Ren Y. et al.: Chem. Eng. J., 2012, 210, 96.

[20] Solcimani M., Naghizadch R., Mirhabibi A. et al.: Iranian J. Mat. Sci. Eng., 2012, 9, 43.

[21] Rios C., Willimas C. and Fullen M.: Appl. Clay Sci., 2009, 42, 446.

[22] Wibowo W., Ariyanto A. and Sekarini S.: Middle East J. Sci. Res., 2010, 5, 435.

[23] Cundy C. and Cox P.: Chem. Rev., 2003, 103, 663.

[24] Flanigen E.: Structural Analysis by Infrared Spectroscopy [in:] Rabo J. (Ed.), Zeolite Chemistry and Catalysis. ACS, Washington 1976.

[25] Zhang A., Li Z. et al.: Appl. Surf. Sci., 2008, 254, 6298.

[26] Thommes M.: Chemie Ingennieur Technik, 1010, 82, 1059.

[27] Sing K., Everett D., Haul R. et al.: Pure Appl. Chem., 1985, 57, 603.