Physical Sorption of Molecular Hydrogen by Microporous Organic Polymers

Ivan Saldan, Yuliia Stetsiv, Viktoriia Makogon, Yaroslav Kovalyshyn, Mykhaylo Yatsyshyn, Oleksandr Reshetnyak
Affiliation: 
Ivan Franko National University of Lviv, 6, Kyryla and Mefodiya St., 79005 Lviv, Ukraine saldanivan@gmail.com
DOI: 
https://doi.org/10.23939/chcht13.01.085
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Abstract: 
The present work describes crosslinked and hypercrosslinked polymers viewed as high surface area materials to adsorb a large amount of molecular hydrogen. Crosslinked polyaniline and polypyrrole were used as examples of hydrogen adsorption by microporous organic polymers. The main reason for physical sorption happening in microporous organic polymers as well the challenges on the way to adjusting the value of hydrogen adsorption enthalpy within the range of 15-20 kJ•mol–1 H2 are highlighted.
References: 

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