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Peculiarities of NMR 13C spectra of benzoic acid and saturated alkylbenzoates. I. Chemical shift of benzoyl fragment hydrocarbon atoms

Volodymyr Mizyuk, Volodymyr Shibanov, Lesya Kobrin, Galyna Marshalok and Georgiy Elagin
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It has been shown that chemical shift of 5 types of carbon nuclei of benzoyl fragment in saturated alkylbenzoates depends upon alkyl radical degree of branching near α-carbon atom of alkoxyl group. Typical values of chemical shifts of five nuclei for primary, secondary and tertiary alkylbenzoates have been admitted

[1] Mizyuk V., Elagin G., Shybanov V. and Kobryn L.: Visnyk Cherkaskogo Universytetu, 2006, 87, 148.

[2] Shybanov V., Mizyuk V. and Kobryn L.: Voprosy khimii i khim.techn., 2005, 5, 51.


[4] Mizyuk V., Shybanov V. and Marshalok I.: Zh.Org.Khim., 1994, 30, 601.

[5] Mizyuk V., Shybanov V. and Marshalok I.: Zh.Org.Khim., 1998, 34, 699.