Error message

  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).

Peculiarities of Activity Renovation of Zeolite Catalysts Coked in Hexane Cracking

Lyubov Patrylak, Oleksandra Pertko
Affiliation: 
1 Institute of Bioorganic Chemistry and Petrochemistry of National Academy of Sciences of Ukraine 1, Murmans'ka St., 02660 Kyiv, Ukraine lkpg@ukr.net
DOI: 
https://doi.org/10.23939/chcht12.04.538
AttachmentSize
PDF icon full_text.pdf144.49 KB
Abstract: 
The initial activity of acid zeolites in n-hexane cracking and influence of their regeneration depth on residual activity using the method of discrete-consecutive coke micro oxidation have been investigated. It was found that oxidation by 5-10 pulses of oxygen properly reflects the activity of catalysts based on faujasite and pentasil, while for mordenite which has increased susceptibility to blocking of channels by coke, such quantity of oxygen is not enough.
References: 

[1] Wojciechowski B., Corma A.: Catalytic Cracking: Catalysis, Chemistry, and Kinetics. Marcel Dekker, Inc. New York 1986.
[2] Ocelli M., O'Connor P. (Eds.): Fluid Cracking Catalysts. Marcel Dekker, Inc. New York 1997.
[3] Nishimura Y.: Adv. Porous. Mater., 2017, 5, 17. https://doi.org/10.1166/apm.2017.1120
[4] Corma A., Corresa E., Mathieu Y. et al.: Catal. Sci. Technol., 2017, 7, 12. https://doi.org/10.1039/C6CY01886F
[5] Groten W., Wojciechowski B.: J. Catal., 1990, 122, 362. https://doi.org/10.1016/0021-9517(90)90290-Z
[6] Cerqueira H., Caeiro G., Costa L., Ramôa Ribeiro F.: J. Mol. Catal. A, 2008, 292, 1. https://doi.org/10.1016/j.molcata.2008.06.014
[7] Cumming K., Wojciechowski B.: Sci. Eng., 1996, 38, 101. https://doi.org/10.1080/01614949608006455
[8] Den Hollander M., Makkee M., Moulijn J.: Catal. Today, 1998, 46, 27. https://doi.org/10.1016/S0920-5861(98)00348-4
[9] Patrylak L.: Adsorp. Sci. Technol., 2000, 18, 399. https://doi.org/10.1260/0263617001493512
[10] Gusev A., Psarras A., Triantafyllidis K. et al.: Molecules, 2017, 22, 1784. https://doi.org/10.3390/molecules22101784
[11] Patrylak K., Patrylak L., Ivanenko V. et al.: Theoret. Exp. Chem., 2010, 46, 256. https://doi.org/10.1007/s11237-010-9149-7
[12] Argyle M., Bartholomew C.: Catalysts, 2015, 5, 145. https://doi.org/10.3390/catal5010145
[13] Guisnet M., Magnoux P.: Appl. Catal. A, 2001, 212, 83. https://doi.org/10.1016/S0926-860X(00)00845-0
[14] Bauer F., Karge H.: Mol. Sieves., 2007, 5, 249. https://doi.org/10.1007/3829_005.
[15] Gil B., Mierzynska K., Szczerbinska M., Datka J.: Micropor. Mesopor. Mater., 2007, 99, 328. https://doi.org/10.1016/j.micromeso.2006.09.025
[16] Vogt E., Weckhuysen B.: Chem. Soc. Rev., 2015, 44, 7342. https://doi.org/10.1039/C5CS00376H
[17] Ivanenko V., Voloshyna Yu., Okhrimenko M.: Theoret. Exp. Chem., 2009, 45, 198. https://doi.org/10.1007/s11237-009-9086-5
[18] Patrylak К., Patrylak L., Pertko O. et al.: Curr. Catal., 2016, 5, 108. https://doi.org/10.2174/2211544705666160322235846
[19] Okhrimenko M.: PhD thesis, Institute of Bioorganic Chemistry, Kyiv 2005.
[20] Umansky B., Hall W.: J. Catal., 1990, 124, 97. https://doi.org/10.1016/0021-9517(90)90106-T