Measurement and Correlation of Isobaric Vapor-Liquid Equilibrium Data for Water + 2-Azido-N,N-Dimethylethanamine System at 4 kPa

Hosein Rouhandeh1, Shahram Ghanbari Pakdehi1
Affiliation: 
1 Faculty of Chemistry & Chemical Engineering, Malek Ashtar University of Technology, P.O. Box: 16765/3454, Tehran, Iran sh_ghanbari73@yahoo.com
DOI: 
https://doi.org/10.23939/chcht15.02.226
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Abstract: 
Isobaric vapor-liquid equilibrium (VLE) data for binary system of water + 2-azido-N,N-dimethylethanamine (DMAZ) was measured at 4 kPa. The results showed an azeotropic point at x1 = 0.985 and T = 302.17 K. The data was correlated with nonrandom two-liquid (NRTL), Wilson and universal quasi-chemical activity coefficient (UNIQUAC) models for the liquid phase. A comparison of the model performances was made using of the criterion of the average absolute deviation, standard deviation and mean standard deviation in boiling-point temperature. The results indicated that the NRTL activity coefficient model satisfactorily correlated the VLE data.
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