Kinetic Regularities of Hydroxy(poly)alkyleneoxy(meth)acrylates Acylation by Phthalic Anhydride

Andrii Gladii, Fedir Tsyupko, Igor Polyugyn, Iosyp Yatchyshyn and Marta Laruk
Affiliation: 
Lviv Polytechnic National University 12, St. Bandera str., 79013 Lviv, Ukraine
DOI: 
https://doi.org/10.23939/chcht09.03.267
AttachmentSize
PDF icon full_text.pdf248.29 KB
Abstract: 
The kinetics of non-catalytic and catalytic processes of 2-hydroxyethylmethacrylate (HEMA) and hydroxyhexaoxypropylacrylate (PPA6) bulk acylation by phthalic anhydride (PA) has been investigated. The product of PA and PPA6 interaction has been synthesized for the first time. The structure of the synthesized compounds has been confirmed by IR-spectroscopy and molar refraction.
References: 

[1] Hanehara S. and Yamada K.: Cem. Contr. Res., 2008, 38, 175.
https://doi.org/10.1016/j.cemconres.2007.09.006

[2] Ran Q., Miao Ch., Liu J., Wu S. and Shen J.: Mat. Trans., 2006, 47, 1599.
https://doi.org/10.2320/matertrans.47.1599

[3] Kurdowski W.: Cement and Concrete Chemistry, Springer, New York 2014.
https://doi.org/10.1007/978-94-007-7945-7

[4] Auschra C., Pennewiss H., Boemke U. and Neusius M.: Pat. US 6080794, Publ. Jun. 27, 2000.

[5] Bruchmann B., Eichhom A. and Guzmann M.: Pat. US 8618180B2, Publ. Dec. 31, 2013.

[6] Fock J. and Rott H.: Pat. US 4678599, Publ. Jul. 7, 1987.

[7] Taylor G.: Pat. US 5609794, Publ. Mar. 11, 1997.

[8] Stephenson W.: Pat. US 4968449, Publ. Nov. 6, 1990.

[9] Kelland M.: Production Chemicals for the Oil and Gas Industry. Taylor & Francis Group, LLC, London 2009.
https://doi.org/10.1201/9781420092974

[10] Shekhter Y. and Kreyn S.: Poverkhnostno-Aktivnye Veshchestva iz Neftianogo Syrya. Khimiya, Moskwa 1971.

[11] Sedlakova Z., Bouchal K. and Ilavsky M.: Die Ang. Makr. Chem., 1992, 201, 33.

[12] Baranovska O.: Zakonomirnosti Syntezu Esteriv i Eteriv. NVF "Ukrainski tekhnologii", 2007.

[13] Gladii A., Tsiupko F., Polyuzhyn I. et al.: Visnyk Nats. Univ. Lviv Polytech., 2014, 787, 17.

[14] Pikh Z.: Teoriya Khimichnykh Procesiv Organichnogo Syntezu. Nats. Univ. "Lvivska Polytechnika", Lviv 2011.

[15] Gladii A., Bereza V., Tsiupko F. and Yatchyshyn Y.: Proc. 3rd Int. Conf. of Young Scientists CCT-2013, Ukraine, Lviv 2013, 88.

[16] http://www.acdlabs.com/resources/freeware/chemsketch/