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IR-Study of Silanol Modification of Ethylene Copolymers

Svetlana Rusanova1, Oleg Stoyanov1, Svetlana Sofina1 and Gennady Zaikov2
Affiliation: 
1Kazan State Technological University, 68, K. Marx str., 420015 Kazan, Tatarstan, Russia; 2Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4, Kosygina str., 119991 Moscow, Russia
DOI: 
https://doi.org/10.23939/chcht07.01.023
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Keywords:

Abstract: 
The chemical interaction of organosilicon compounds and copolymers of ethylene with vinylacetate and copolymers of ethylene with vinylacetate and maleic anhydride was studied by IR-spectroscopy absorption and attenuated total reflection (ATR). An enrichment of the surface layers of polymers by siloxane phase was found, that may be useful in the design of the chemical structure of adhesive materials for different purposes.
References: 

[1] Rusanova S.: PhD thesis, Kazanski Gos. Texnol. Univ, Kazan 2000.

[2] Stoyanov O., Rusanova S., Petukhova O. and Remisov A.: Zh. Prikl. Khimii, 2001, 74, 1174.

[3] Bounor-Legaré V., Ferreira I., Verbois A. et al.: Polymer, 2002, 43, 6085.
https://doi.org/10.1016/S0032-3861(02)00364-6

[4] Bogatyrev V., Maksakova G., Villevald G. and Logvinenko V.: Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim., 1986, 2, 104.

[8] Belopolskaya T.: Vysokomol. Soed., 1972, 14, 640.