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Influence of Bi3+ Ions on Kinetics of Lead Dioxide Electrodeposition from Methanesulfonate Electrolytes

Olesia Shmychkova, Amina Magomedova, Dmitriy Girenko, Tatiana Luk’yanenko and Alexander Velichenko
Ukrainian State University of Chemical Technology 8, Gagarin Ave., 49005 Dnipropetrovsk, Ukraine;
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Influence of bismuth ions on kinetics of lead dioxide electrodeposition from methanesulfonate electrolytes on Pt-electrode was studied. Experimental results are interpreted to be consistent with the mechanism proposed previously for lead dioxide electrodeposition in literature. The presence of bismuth ions in the electrodeposition solution causes decreasing rate constants of lead dioxide formation due to additive adsorption.

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