Influence of Amino Acids and Alcohols on Catalytic Oxidation of Cyclohexane

Anatolij Ludyn1, Volodymyr Reutskyy1, Viktor Reutskyy1, Yurij Hrynchuk1
Affiliation: 
1 Lviv Polytechnic National University, 12, S. Bandery St., 79013 Lviv, Ukraine anatolii.m.ludyn@lpnu.ua
DOI: 
https://doi.org/10.23939/chcht15.03.352
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Abstract: 
Conducted experiments and collected data show that use of catalytic systems that contain individual amino acids and industrial catalyst – solution of cobalt naphtenate with cyclohexanone – have certain influence on the process of liquid-phase homogeneous oxidation of cyclohexane. The results of spectral studies of binary catalytic systems based on NC using additives of different nature (alcohols and nitrogen-containing modifiers) allow us to propose structural formulas of catalytic complexes.
References: 

[1] Ivashchuk O.: Visnyk Nats. Univ. Lvivska Polytechnika, 2012, 726, 172.

[2] Ivashchuk O., Reutskyy V., Mudryy S. et al.: Chem. Chem. Technol., 2012, 6, 339. https://doi.org/10.23939/chcht06.03.339
https://doi.org/10.23939/chcht06.03.339

[3] Reutskyy V., Ivashchuk O., Mudryj S., Suprun O.: Abstracts of Actual Problems of Chemistry and Technology of Organic Substances, Lviv 2012, 24.

[4] Riley C.: Open Catal. J., 2012, 5, 8. https://doi.org/10.2174/1876214X01205010008
https://doi.org/10.2174/1876214X01205010008

[5] Ozeryanskii V., Gorbacheva A., Pozharskii A., Vlasenko M.: Org. Biomol. Chem., 2015, 13, 8524. https://doi.org/10.1039/C5OB01065A
https://doi.org/10.1039/C5OB01065A

[6] Suprun O., Reutskyy V., Ivashchuk O., Mudryj S.: Visnyk Nats. Univ. Lvivska Polytechnika, 2014, 787, 187.

[7] Arshadi M., Ghiaci M. et al.: J. Mol. Catal. A-Chem., 2011, 338, 71

[8] Melnyk Y., Reutskyy V., Melnyk S. et al.: Chem. Eng. Transact., 2011, 24, 163. https://doi.org/10.3303/CET1124028

[9] Malhotra S., Jaspal D., Malvia A.: Arab. J. Chem., 2019, 12, 1247. https://doi.org/10.1016/j.arabjc.2014.10.048
https://doi.org/10.1016/j.arabjc.2014.10.048

[10] Xie H., Hayes T., Gathergood N.: Catalysis of Reactions by Amino Acids [in:] Hughes A. (Ed.), Amino Acids, Peptides and Proteins in Organic Chemistry: Modified Amino Acids, Organocatalysis and Enzymes, V 2. Wiley-VCH Verlag GmbH 2010. https://doi.org/10.1002/9783527631780.ch7
https://doi.org/10.1002/9783527631780.ch7

[11] Yan N., Y. Wang: Chem, 2019, 2, 739 https://doi.org/10.1016/j.chempr.2019.03.016
https://doi.org/10.1016/j.chempr.2019.03.016

[9] Kazicyna L., Kupletskaya N.: Ispolzovanie UF-, IK-I JaMR- spectroskopii v organicheskoj himii, Vyshaya shkola, Moskva 1971.

[10] Mironov V., Yankovkiy S.: Spectrografia v Organicheskoi Khimii. Khimia, Moskva 1985.