Formation of Elastomeric Composition Properties in the Presence of Bioingredient
Affiliation:
1 State Higher Educational Institution "Ukrainian State University of Chemical Technology"
8, Gagarina Ave., Dnipro 49005, Ukraine.
2 ROSAVA TIERS Limited Liability Company
91, Levanevskoho St., Bila Tserkva 09108, Ukraine.
sokolovalina18@gmail.com
DOI:
https://doi.org/10.23939/chcht17.01.088
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Keywords:
Abstract:
Peculiarities of formation of technological, vulcanization, dynamic, relaxation, and physicomechanical properties of elastomeric composition used for the tread production have been studied in the presence of bioingredient as a plasticizer-softener. Bioingredient is an organic component of sunflower oil winterization by-product (OSSO product). It was found that the OSSO product increases the cohesive strength of the rubber compound by 1.5 times in comparison with the industrial petrochemical lubricants. Under the same vulcanization conditions, the bioingredient provides 30–40 % higher resistance to reversion and relaxation processes at 373 K, lower dynamic losses, as well a high level of physical and mechanical characteristics.
References:
[1] Ovcharov, V.I.; Burmistr, M.V.; Tyutin, V.A.; Verbas, V.V.; Smirnov, A.G.; Naumenko, A.P. Svojstva rezinovyh smesej i rezin: ocenka, regulirovanie, stabilizaciya; SANT-TM: M., 2001.
[2] Prokopchuk, N.R.; Kayushnikov, S.N.; Vishnevskij, K.V. Tehnologicheski aktivnye dobavki v sostave elastomernyh kompozicij (obzor). Polimernye materialy i tehnologii [Online] 2016, 2, № 3, 6-23. (accessed Dec 22, 2021).
https://doi.org/10.32864/polymmattech-2016-2-3-6-23
[3] Frolikova, V.G.; Donskaya, M.M.; Yalovaya, L.I.; Pichugin, A.M.; Vishnyakov, I.I. Sources of Carcinogenic and Toxic
Substances in the Production and Service of Tyres. Kauchuk i Rezina 2008, 36, 20-27. https://doi.org/10.1177/0307174X0903600805
https://doi.org/10.1177/0307174X0903600805
[4] Baensch-Baltruschat, B.; Kocher, B.; Stock, F.; Reifferscheid, G. Tyre and Road Wear Particles (TRWP) - A Review of Generation, Properties, Emissions, Human Health Risk, Ecotoxicity, and Fate in the Environment. Sci. Total Environ. 2020, 733, 137823. https://doi.org/10.1016/j.scitotenv.2020.137823
https://doi.org/10.1016/j.scitotenv.2020.137823
[5] Ovcharov, V.I.; Sokolova, L.O.; Rzymski, W.M.; Grishenko, V.K. Efektyvnist chetvertynnykh amoniyevykh solej v binarnykh systemah z inshymy pryskoryuvachamy vulkanizatsii polidiyeniv. Polimernyi zhurnal [Online] 2014, 36, 85-90. http://nbuv.gov.ua/UJRN/Polimer_2014_36_1_13 (accessed Dec 22, 2021).
[6] Ovcharov, V.I.; Sokolova, L.O.; Ohtina, O.V.; Grishenko, V.K.; Barancova, A.V. Spoluky z kvaternizovanym atomom nitrogenu na osnovi biosyrovyny v procesakh sirchanoi vulkanizatsii polidiyeniv. Polimernyj zhurnal [Online] 2014, 36, 199-206. http://nbuv. gov.ua/UJRN/Polimer_2014_36_2_15 (accessed Dec 22, 2021).
[7] Ovcharov, V.I.; Sokolova, L.O.; Yusupova, L.R.; Grishenko, V.K.; Barancova, A.V. Vlastyvosti polidiyeniv za nayavnosti
chetvertynnykh amoniyevyh solej iz syrovyny roslynnoho
pokhodzhennya yak aktyvatoriv vulkanizatsii. Polimernyj zhurnal [Online] 2017, 39, 260-270. http://nbuv.gov.ua/UJRN/Polimer_2017_39_4_11 (accessed Dec 22, 2021).
https://doi.org/10.1007/s35139-017-0103-0
[8] Ovcharov, V.I.; Sokolova, L.A.; Grishchenko, V.K.; Barantsova, A.V.; Kovalenko, V.L.; Kotok, V.A. Quaternary Ammonium
Compound from Bio-Source in the Vulcanization System
of Elastomeric Compositions. J. Eng. Appl. Sci. [Online] 2020, 15, 2266-2278. https://www.researchgate.net/publication/346612832_QUATERNARY_AMMONIUM_C... (accessed Dec 22, 2021).
[9] Ogbebor, O.J.; Okwu, U.N.; Okieimen, F.E.; Okuonghae D. Phisiko-Mechanical Properties Of Elastomers Based on Natural Rubber Filled with Silica and Clay. Chem. Ind. Chem. Eng. Q. 2010, 16, 373-378. https://doi.org/10.2298/CICEQ100110038O
https://doi.org/10.2298/CICEQ100110038O
[10] Chang, B.P.; Gupta, A.; Muthuraj, R.; Mekonnen T.H.
Bioresourced Fillers for Rubber Composite Sustainability: Current Development and Future Opportunities. Green Chem. 2021, 23, 5337-5378. https://doi.org/10.1039/D1GC01115D
https://doi.org/10.1039/D1GC01115D
[11] Kablov, V.F.; Aksenov, V.I. Sovremennye tendentsii
primeneniya kauchukov i napolnitelej v recepture rezin.
Promyshlennoe proizvodstvo i ispolzovanie elastomerov
2018, 3, 24-34.
[12] Sekifuji, R.; Tateda, M. Study of the Feasibility of a Rice Husk Recycling Scheme in Japan to Produce Silica Fertilizer for Rice Plants. Sustain. Environ. Res. 2019, 29, 11. https://doi.org/10.1186/s42834-019-0011-x
https://doi.org/10.1186/s42834-019-0011-x
[13] Costa, J.A.S.; Paranhos, C.M. Systematic Evaluation of Amorphous Silica Production from Rice Husk Ashes. J. Clean. Prod. 2018, 192, 688-697. https://doi.org/10.1016/j.jclepro.2018.05.028
https://doi.org/10.1016/j.jclepro.2018.05.028
[14] Nghia, N.H.; Zenitova, L.A.; Quang, D.L.; Truyen, D.N. The Method of Obtaining Amorphous Nanosized Silicon Dioxide from Rice Production Waste. Ecol. Ind. Russ. 2019, 23, 30-35. https://doi.org/10.18412/1816-0395-2019-4-30-35
https://doi.org/10.18412/1816-0395-2019-4-30-35
[15] Hura, D.V.; Soroka, P.I.; Cheremysinova, A.A. Integrated Process of Obtaining Heat and Silicon(IV) Oxide from Siliceous Plant Materials. Chem. Mater. Eng. 2014, 2, 72-78. https://doi.org/10.13189/cme.2014.020303
https://doi.org/10.13189/cme.2014.020303
[16] Azat, S.; Korobeinyk, A.V.; Moustakas, K.; Inglezakis, V.J. Sustainable Production of Pure Silica from Rice Husk Waste in Kazakhstan. J. Clean. Prod. 2019, 217, 352-359. https://doi.org/10.1016/j.jclepro.2019.01.142
https://doi.org/10.1016/j.jclepro.2019.01.142
[17] Sekifuji, R.; Van, Ch. L.; Tateda M.; Takimoto H.
Sustainability of a Rice Husk Recycling Scheme. Int. J. Recycl. Org. Waste Agric. 2020, 9, 411-421.
[18] Khan, H.; Amin, M.; Ali, M.; Iqbal, M.; Yasin, M. Effect of Micro/Nano-SiO2 on Mechanical, Thermal, and Electrical Properties of Silicone Rubber, Epoxy, and EPDM Composites for Outdoor Elec-Trical Insulations. Turk. J. Elec. Eng. & Comp. Sci. 2017, 25, 1426-1435. https://doi.org/10.3906/elk-1603-20
https://doi.org/10.3906/elk-1603-20
[19] Akçakale, N. Effects of Carburized Rice Husk Powders on Physical Properties of Elastomer based Materials. Kautschuk Gum-mi Kunststoffe [Online] 2017, 70, 49-54. https://hdl.handle.net/20.500.12491/9134 (accessed Dec 22, 2021).
[20] ACS Publications Home Page. https://www.tirereview.com/rice-is-nice-as-silica-for-pirelli-tires/ (accessed 2021-12-22).
[21] Gura, D.V.; Soroka, P.I. Opredelenie tekhnolohicheskikh
parametrov processa polucheniya kremnii-uhlerodnykh kompozitsii iz otkhodov risovoho proizvodstva metodami termodinamicheskikh i kineticheskikh issledovanii. Praci Odeskogo politehnichnogo universitetu [Online] 2013, 3, 310-314. http://nbuv.gov.ua/UJRN/Popu_2013_3_63 (accessed Dec 22, 2021).
[22] Ovcharov, V.I.; Sokolova, L.O.; Gura, D.V.; Soroka, P.G. Vlastyvosti elastomernykh kompozycii za nayavnosti kremnii-vugletsevoho napovnyuvacha z biosyrovyny. Voprosy himii i himicheskoj tehnologii [Online] 2014, 1, 61-65. http://vhht.dp.ua/wp-content/uploads/pdf/2014/1/14.pdf (accessed Dec 22, 2021).
[23] Ovcharov, V.I.; Sokolova, L.A.; Yusupova, L.R.; Tertyshnyj, O.A. Elastomernye kompozitsii s dioksidom kremniya,
poluchennym iz risovoi shelukhi. Voprosy himii i himicheskoj tehnologii [Online] 2016, 5-6, 87-92. http://vhht.dp.ua/wp-content/uploads/pdf/2016/5/Ovcharov.pdf (accessed Dec 22, 2021).
[24] Ovcharov, V.I.; Sukhyy, K.M.; Sokolova, L.A.; Kalinyuk, V.L.; Tertyshnyy, O.A.; Yusupova, L.R.; Belyanovskaya, E.A. The Use of the Heat-Treated Rice Husks as Elastomeric Compositions Fillers. Vopr. Khimii i Khimicheskoi Tekhnologii [Online] 2018, 3, 79-89. http://vhht.dp.ua/wp-content/uploads/pdf/2018/3/Ovcharov.pdf (accessed Dec 22, 2021).
[25] Gridneva, T.; Kravchenko, A.; Barsky, V.; Gurevina N.
Obtaining of High Purity Amorphous Silicon Dioxide from Rice Husk. Chem. Chem. Technol. 2016, 10, 499-505. https://doi.org/10.23939/chcht10.04.499
https://doi.org/10.23939/chcht10.04.499
[26] Rudnyeva, L.L.; Buhkalo, S.I.; Lakiza, O.V.; Chervakov, O.V. Roslynni vosky yak modyfikatory vlastyvostei elastomernykh i polimernykh materialiv. Vopr. Khimii i Khimicheskoi Tekhnologii 2021, 1, 90-100. https://doi.org/10.32434/0321-4095-2021-134-1-90-100
https://doi.org/10.32434/0321-4095-2021-134-1-90-100
[27] Reznichenko, S.V.; Morozova, Yu.L. Bolshoj spravochnik rezinshika; Tehinform, MAI, 2012.
[28] Kachkurkina, I.; Ovcharov, V.; Schevchenko O. The Usage of Oil Refining Industry Waste as Vulcanization Active Ingredient of Elastomeric Compositions. Chem. Chem. Technol. 2009, 3,
https://doi.org/10.23939/chcht03.04.295
295-300. https://doi.org/10.23939/chcht03.04.295
https://doi.org/10.23939/chcht03.04.295
[29] Bastioli K.; Kapucci L.; Magistrali P.; Gesti G.S.; Viola D.T.; Savini D.; Bachchelli F. Pokhidni roslynnykh olii yak olyyy-napovnyuvachi dlya elastomernyh kompoztscii. UA 110123, 25 listopada, 2015.
[30] Dick, J.S. How to Improve Rubber Compounds: 1800 Experi-mental Ideas for Problem Solving; Hanser Publishers, 2014. https://doi.org/10.3139/9781569905340.002
https://doi.org/10.3139/9781569905340.002
[31] Kayushnikov, S.N.; Prokopchuk, N.R.; Uss, E.P.; Karmanova, O.V. Svojstva shinnykh rezin s tsinkosoderzhashchimi
tekhnolohicheskimi dobavkami. Vestnik VGUIT 2017, 79, 126-135. https://doi.org/10.20914/2310-1202-2017-3-126-135
https://doi.org/10.20914/2310-1202-2017-3-126-135
[32] Samarth, N.B.; Mahanwar, P.A. Modified Vegetable Oil Based Additives as a Future Polymeric Material-Review. Open J. Org. Polym. Mater. 2015, 5, 1-22. https://doi.org/10.4236/ojopm.2015.51001
https://doi.org/10.4236/ojopm.2015.51001
[33] Ivashchuk, O.; Hlukhaniuk, A.; Semenyshyn, Y.; Chyzhovych, R.; Kuzminchuk, T.; Khomyak, S. Influence of Extraction Conditions on Qualitative Composition of Vegetable Oils. Chem. Chem. Technol. 2021, 15, 233-238. https://doi.org/10.23939/chcht15.02.233
https://doi.org/10.23939/chcht15.02.233
[34] Semenyshyn, Y.; Atamanyuk, V.; Rymar, T.; Ivashchuk, O.; Hlukhaniuk, A. Mass Transfer in the Solid-Liquid System: Mecha-nism and Kinetics of the Extraction Process. Chem. Chem. Technol. 2020, 14, 121-128. https://doi.org/10.23939/chcht14.01.121
https://doi.org/10.23939/chcht14.01.121
[35] Sunflower: Chemistry, Production, Processing, and Utilization; Enrique, M.-F.; Dunford, N.T.; Salas, J.J., Eds.; Academic Press and AOCS Press, 2015.
[36] Ovcharov, V.I.; Mironyuk, O.V.; Sokolova, L.O.; Suha, I.V. Zastosuvannya produktiv ochishchennya i vidpalyuvannya vy-korystanoho adsorbentu ochyshchennya sonyashnykovoyi oliyi yak napovnyuvachiv elastomernykh kompozitsii. Vopr. Khimii i Khimicheskoi Tekhnologii 2020, 5, 53-62. https://doi.org/10.32434/0321-4095-2020-132-5-53-62
https://doi.org/10.32434/0321-4095-2020-132-5-53-62
[37] Structure-Function Analysis of Edible Fats; Marangoni, A.G., Ed.; Published by Elsevier Inc. 2018. https://doi.org/10.1016/C2017-0-00579-7
https://doi.org/10.1016/C2017-0-00579-7
[38] Ovcharov, V.I.; Yusupova, L.R.; Murashevich, B.V.; Toropin, M.V. Ocinka mozhlyvosti vykorystannya vtorynnoyi mineralnoyi syrovyny vyrobntstva sonyashnikovoyi oliyi u skladah
elastomernykh kompozytsii. Vopr. Khimii i Khimicheskoi Tekhnologii 2019, 2, 99-105. https://doi.org/10.32434/0321-4095-2019-123-2-99-105
https://doi.org/10.32434/0321-4095-2019-123-2-99-105
[39] Cheremisinoff, N.P.; Cheremisinoff, P.N. Elastomer Technology Handbook; CRC Press, 2019.
https://doi.org/10.1201/9780138758851
[40] Current Topics in Elastomers Research; Bhowmick, A.K. Ed.; CRC Press 2019.
[41] Oldham, E.W.; Baker, L.M.; Craytor M.W. Determination of Free Sulfur in Rubber. Ind. Eng. Chem. Anal. Ed. 1936, 8, 41-42. https://doi.org/10.1021/ac50099a017
https://doi.org/10.1021/ac50099a017
[42] Ou, H.; Sahli, M.; Barriere, T.; Gelin, J.-C. Determination of the Activation Energy of Silicone Rubbers Using Different Kinetic Analysis Methods. MATEC Web of Conferences 2016, 80, 16007. https://doi.org/10.1051/matecconf/20168016007
https://doi.org/10.1051/matecconf/20168016007
[43] Zhao, A.; Shi, X.-Y.; Sun, S.-H.; Zhang, H.-M.; Zuo, M.; Song, Y.-H.; Zheng, Q. Insights into the Payne Effect of Carbon Black Filled Styrene-butadiene Rubber Compounds. Chinese J. Polym. Sci. 2021, 39, 81-90. https://doi.org/10.1007/s10118-020-2462-2
https://doi.org/10.1007/s10118-020-2462-2
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