Error message

  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).

Experimental and Theoretical Investigations of Anti-Corrosive Properties of Thymol

Victoria Vorobyova1, Olena Chygyrynets’1, Margarita Skiba2, Tatiana Overchenko1
Affiliation: 
1 National Technical University of Ukraine «Igor Sikorsky Kyiv Polytechnic Institute», 37, Peremogy Ave., 03056 Kiev, Ukraine vorobyovavika1988@gmail.com 2 Ukrainian State Chemical-Engineering University, 8, Gagarina Ave., 49066 Dnipro, Ukraine
DOI: 
https://doi.org/10.23939/chcht13.02.261
AttachmentSize
PDF icon full_text.pdf641.52 KB
Abstract: 
The inhibition effect of thymol during the early stage of steel corrosion under adsorbed thin electrolyte layers was investigated. Its vapor corrosion inhibition property was evaluated under simulated operational conditions. Electrochemical techniques complemented by FTIR and SEM surface analyses were used to evaluate the composition and characteristics of the layers. The results indicate that thymol can form a protective film on the metal surface, which protects the metal against further corrosion. Quantum chemical calculations studies were also performed to support weight loss and electrochemical experimental observations.
References: 

[1] Zhang D-Q., Gao L-X., Zhou G-D.: Surf. Coat. Technol., 2010, 204, 1646. https://doi.org/10.1016/j.surfcoat.2009.10.054
[2] Zhang D-Q., An Z-X., Pan Q-Y. et al.: Corros. Sci., 2006, 48, 1437. https://doi.org/10.1016/j.corsci.2005.06.007
[3] Sudheer A., Quraishi E., Eno E., Natesan M.: Int. J. Electrochem. Sci., 2012, 7, 7463.
[4] Quraishi M., Jamal D.: Corrosion, 2002, 58, 5, 387. https://doi.org/10.5006/1.3277627
[5] Montemor M.: Act. Protect. Coat., 2016, 233, 107. https://doi.org/10.1007/978-94-017-7540-3_6
[6] Chygyrynets’ E., Vorobyova V.: Chem. Chem. Technol., 2014, 8, 235.
[7] Vorob’iova V., Chyhyrynets’ O., Vasyl’kevych O.: Mater. Sci., 2015, 50, 726. https://doi.org/10.1007/s11003-015-9778-z
[8] Chyhyrynets O.,Vorob'iova V.: Mater. Sci., 2013, 49, 318. https://doi.org/10.1007/s11003-013-9617-z
[9] Poongothai N., Rajendran P., Natesan M. et al.: Indian J. Chem. Technol., 2005, 12, 641.
[10] Premkumar P., Kannan K., Natesan M.: Asian J. Chem., 2008, 20, 445.
[11] Premkumar P., Kannan K., Natesan M.: J. Metall. Mater. Sci., 2008, 50, 227.
[12] Li X., Deng S., Fu H., Xie X.: Corros. Sci., 2014, 78, 29. https://doi.org/10.1016/j.corsci.2013.08.025
[13] Leygraf C., Wallinder I.,Tidblad J., Graedel T.: Atmospheric Corrosion. John Wiley & Sons, Inc., Hoboken 2016.
[14] Kaya S., Tüzün B., Kaya C., Obot I.: J. Taiwan Inst. Chem. Eng., 2016, 58, 528. https://doi.org/10.1016/j.jtice.2015.06.009
[15] Gece G.: Corros. Sci., 2008, 50, 11, 2981. https://doi.org/10.1016/j.jtice.2015.06.009
[16] Koopmans T.: Physica, 1934, 1, 104. https://doi.org/10.1016/S0031-8914(34)90011-2
[17] Kovacevic N., Kokalj A.: Corros. Sci., 2011, 53, 3, 909. https://doi.org/10.1016/j.corsci.2010.11.016
[18] Parr R., Pearson R.: J. Am. Chem. Soc., 1983, 105, 7512. https://doi.org/10.1021/ja00364a005
[19] Parr R., Donnelly R., Lewy M., Palke W.: J. Chem. Phys., 1978, 68, 3801. https://doi.org/10.1063/1.436185
[20] Pearson R.: Proc. Nats. Acad. Sci. USA, 1986, 83, 8440.
[21] Chattaraj P., Sarkar R., Roy D.: Chem. Rev., 2006, 106, 2065. https://doi.org/10.1021/cr040109f
[22] Parr R., von Szentpaly L., Liu S.: J. Am. Chem. Soc. 1999, 121, 1922. https://doi.org/10.1021/ja983494x
[23] Kaya S., Kaya C.: Comput. Theor. Chem., 2015, 1052, 42. https://doi.org/10.1016/j.comptc.2014.11.017
[24] HyperChemTM, Hypercube, Inc., 1994
[25] Rosliza R. et al.: J. Appl. Electrochem., 2010, 40, 833. https://doi.org/10.1007/s10800-009-0066-1
[26] Ferreira M., Varela H., Torresi R., Tremiliosi-Filho G.: Electrochim. Acta, 2006, 52, 434. https://doi.org/10.1016/j.electacta.2006.05.025
[27] Lukovits I., Kálmán E., Zucchi F.: Corrosion. 2001, 57, 3. https://doi.org/10.5006/1.3290328