Error message

  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).

Epoxy Composites Filled with Natural Calcium Carbonate. 2. Epoxy Composites Obtained in the Presence of Monomethacrylic Derivative of Epidian-6 Epoxy Resin

Michael Bratychak1, Olena Astakhova1, Olena Shyshchak1, Maciej Sienkiewicz2, Justyna Kucinska-Lipka2
Affiliation: 
1 Lviv Polytechnic National University 12, S.Bandery St., 79013 Lviv, Ukraine 2 Gdansk University of Technology, 11/12 G. Narutowicza St., 80233 Gdansk, Poland mbratychak@gmail.com
DOI: 
https://doi.org/10.23939/chcht14.03.343
AttachmentSize
PDF icon full_text.pdf1.76 MB

Keywords:

Abstract: 
On the basis of Epidian-6 epoxy resin and methacrylic acid a monomethacrylic derivative of Epidian-6 with free epoxy and methacrylic groups (MMADER) has been synthesized. The structure of MMADER was confirmed by IR spectroscopy. The thermal stability of MMADER has been established. The cross-linking of unfilled epoxy-oligomeric mixtures and mixtures filled with CaCO3 has been studied in the presence of MMADER. By means of IR spectroscopy, the chemistry of the formation of mixtures based on Epidian-5, oligoesteracrylate TGM-3, MMADER and polyethylene polyamine has been established. Physico-mechanical characteristics of epoxy-oligomeric mixtures filled with CaCO3 have been established.
References: 

[1] Nielsen L., Landel R.: Mechanical Properties of Polymers and Composites, 2nd edn. CRC Press, Boca Raton 1993.
[2] Chernin Ch., Smekhov F., Zherdeev Yu.: Epoksidnye Polymery i Kompozitsii. Khimia, Moskva 1982.
[3] Ellis B.: Chemistry and Technology of Epoxy Resins. Blackie Academic and Professional, London 1993.
[4] Hetmanchuk Yu., Bratychak M.: Khimiya i Technologiya Oligomeriv. Vyd-vo Kyiv Univ., Кyiv 2008.
[5] Tang L.-C., Wan Y.-J., Yan D et al.: Carbon, 2013, 60, 16. https://doi.org/10.1016/j.carbon.2013.03.050
[6] Lee J.-Y., Shim M.-J., Kim S.-W.: Mater. Chem. Phys., 1997, 48, 36. https://doi.org/10.1016/S0254-0584(97)80073-9
[7] Ng C., Ash B., Schadler L. et al.: Adv. Compos. Lett., 2001, 10, 101. https://doi.org/10.1177/096369350101000301
[8] Ng C., Schadler L., Siegel R.: Nanostruct. Mater., 1999, 12, 507. https://doi.org/10.1016/S0965-9773(99)00170-1
[9] Tee D., Mariatti M., Azizan A. et al.: Compos. Sci. Technol., 2007, 67, 2584. https://doi.org/10.1016/j.compscitech.2006.12.007
[10] Shi G., Zhang M.-Q., Rong M.-Z. et al.: Wear, 2003, 254, 784. https://doi.org/10.1016/S0043-1648(03)00190-X
[11] Schueler R., Petermann J., Schulte K. et al.: J. Appl. Polym. Sci., 1997, 63, 1741. https://doi.org/10.1002/(SICI)1097-4628(19970328)63:13<1741::AID-APP5>3.0.CO;2-G
[12] Mohan T., Kanny K.: Compos. Part A-Appl. S., 2011, 42, 385. https://doi.org/10.1016/j.compositesa.2010.12.010
[13] Yung K., Zhu B., Yue T. et al.: Compos. Sci. Technol., 2009, 69, 260. https://doi.org/10.1016/j.compscitech.2008.10.014
[14] Leong Y., Abu Bakar M., Mohd Oshak Z. et al.: J. Appl. Polym. Sci., 2004, 91, 3315. https://doi.org/10.1002/app.13542
[15] Shi Q., Wang L., Yu H. et al.: Macromol. Mater. Eng., 2006, 291, 53. https://doi.org/10.1002/mame.200500223
[16] Mustata F., Tudirachi N., Rosu D.: Compos. Part B-Eng., 2012, 43, 702. https://doi.org/10.1016/j.compositesb.2011.11.047
[17] Yu H., Wang L., Shi Q. et al.: Prog. Org. Coat., 2006, 55, 296. https://doi.org/10.1016/j.porgcoat.2006.01.007
[18] He H., Li K., Wang J. et al.: Mater. Design, 2011, 32, 4521. https://doi.org/10.1016/j.matdes.2011.03.026
[19] Bratychak M., Astakhova O., Shyshchak O. et al.: Chem. Chem. Technol., 2019, 13, 360. https://doi.org/10.23939/chcht13.03.360
[20] Odabiashian G., Shvets V.: Laboratornyi Praktikum po Khimii i Technologii Organicheskogo Sinteza. Khimia, Moskva 1982.
[21] Sorokin M., Lialiushko K.: Praktikum po Khimii i Technologii Plenkoobrazuyushikh Veshestv. Khimia, Moskva 1971.
[22] Siggia S.: Quantitative Organic Analysis via Functional Groups. Wiley 1979.
[23] Ivanov V.: Rukovodstvo k Prakticheskim Rabotam po Khimii Polimerov. Izd-vo Leningrad. Univ., Leningrad 1982.
[24] Bashta B., Astakhova O., Shyshchak O., Bratychak M..: Chem. Chem. Technol., 2014, 8, 309. https://doi.org/10.23939/chcht08.03.309
[25] Bratychak M., Shyshchak O., Astakhova O., Ivashkiv O.: Oligomers with Functional Groups Based on Epoxy Resins. Synthesis, Properties and Application. Lviv Polytechnic Publ. House,. Lviv 2019.