Error message

  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).

ELECTROCHEMICAL PROPERTIES OF THE COMPOSITES SYNTHESIZED FROM POLYANILINE AND MODIFIED MWCNT

Yaroslav Kovalyshyn1, Myroslava Konovska1, Chiara Milanese2, Ivan Saldan1,2, Roman Serkiz3, Orest Pereviznyk1, Oleksandr Reshetnyak1, Orest Kuntyi4,
Affiliation: 
1 Ivan Franko National University of Lviv, 6, Kyryla and Mefodia St., 79005 Lviv, Ukraine; 2 Pavia H2 Lab, C.S.G.I. & Department of Chemistry, Physical Chemistry Section, University of Pavia, Viale Taramelli 16, Pavia 27100, Italy 3 Center of Low-Temperature Studies, Ivan Franko National University of Lviv, 50, Dragomanova St., 79005 Lviv, Ukraine 4 Lviv Polytechnic National University, 12 Bandery St., 790013 Lviv, Ukraine
DOI: 
https://doi.org/10.23939/chcht11.03.261
AttachmentSize
PDF icon full_text.pdf2.85 MB
Abstract: 
Electroactive composites made of polyaniline and MWCNT modified by aminobenzene groups were electrochemically synthesized. SEM observation confirms that the composites become more porous as the MWCNT aggregation on the electrode surface gradually increases. Paraboloid dependence of specific electrical conductivity on the MWCNT content was found for the composites with more than 2.0 wt % of MWCNT. Obtained results confirmed a strong relationship between the surface and electrical properties allowing to offer their optimization using different amount of MWCNTs and preparation procedure.
References: 

[1] Volkov S., Kovalchuk E., Ohenko V., Reshentnyak O.: Nanokhimiya. Nanosystemy. Nanomaterialy. Naukova dumka, Kyiv 2008.

[2] Eftekhari A.: Nanostructured Conductive Polymers. Wiley, Weinheim 2010. https://doi.org/10.1002/9780470661338
https://doi.org/10.1002/9780470661338

[3] Chiang J., MacDiarmid A.: Syn. Met., 1986, 13, 193. https://doi.org/10.1016/0379-6779(86)90070-6
https://doi.org/10.1016/0379-6779(86)90070-6

[4] Feast W., Tsibouklis J., Pouwer K. et al.: Polymer, 1996, 37, 5017. https://doi.org/10.1016/0032-3861(96)00439-9
https://doi.org/10.1016/0032-3861(96)00439-9

[5] Abalyayeva V., Bogatyrenko V., Anoshkin A. et al.: Macromol. Comp., 2010, 52, 724.

[6] Kinlen P., Liu J., Ding Y. et al.: Macromolecules, 1998, 31, 1735. https://doi.org/10.1021/ma971430l
https://doi.org/10.1021/ma971430l

[7] Kovalyshyn Y., Gudz Y., Reshetnyak O. et al.: Proceed. Int. Symp. on Functional Materials and Nanotechnologies, Lithuania, Vilnius 2015, 152.

[8] Sementsov Yu., Melezhyk A., Prykhodko D. et al.: Fizika i Khimiya Nanomaterialov i Macromolecularnye Struktury. Naukova dumka, Kyiv 2007.

[9] Maas G., Tanaka M., Sakakura T.: E-eros Encyclopedia of Reagents for Organic Synthesis. Wiley, Chichester 2001.

[10] Dombrovski A., Naydan V.: Organichna Khimiya. Vyd-vo Lviv Nat. Univ., Lviv 1992.

[11] Kovalchuk E., Tomilov A., Krupak A. et al.: Rus. J. Electrochem., 2011, 47, 1125. https://doi.org/10.1134/S1023193511100077
https://doi.org/10.1134/S1023193511100077

[12] Kovalchuk, E., Krupak A., Ohenko V.: Nanostruct. Mater. Sci., 2009, 2, 69.

[13] Vasylchenko O.: PhD thesis, Kharkiv Polytechnic University, Kharkiv 1995.

[14] Pokhodenko V., Krylov V.: Theor. Exp. Chem., 1994, 3, 111. https://doi.org/10.1007/BF00538188
https://doi.org/10.1007/BF00538188

[15] Cai L., Zhou S.: J. Electroanal. Chem., 1997, 421, 45. https://doi.org/10.1016/S0022-0728(96)04836-X
https://doi.org/10.1016/S0022-0728(96)04836-X

[16] Yatsyshyn M., Kovalchuk E.: Praci Nauk. Tovar. im. Shevchenka, 2008, 21, 87.

[17] Iijima S.: Nature, 1991, 354, 56. https://doi.org/10.1038/354056a0
https://doi.org/10.1038/354056a0

[18] Trchova M., Sedenkova I., Konyushenko E. et al.: J. Phys. Chem. B, 2006, 110, 9461. https://doi.org/10.1021/jp057528g
https://doi.org/10.1021/jp057528g