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Effect of Barium Salts on Physico-Chemical and Catalytic Properties of Fe-Te-Mo-Ox catalyst for Oxidative Amonolysis of Isobutyl Alcohol

Vyacheslav Zhyznevskiy, Volodymyr Gumenetskiy, Olena Matskiv and Olena Shyshchak
Lviv Polytechnic National University 12 Bandera str., 79013 Lviv, Ukraine
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The effect of barium salts (nitrate, sulphate, chloride) on the physico-chemical and catalytic properties of Fe:Te:Mo (1:0.85:1) oxide catalyst has been determined for oxidative amonolysis of isobutyl alcohol (IBA) to methacrylonitrile (MAN). The catalyst doped with BaCl2 (Ba/Mo = 0.1) was found to be the best catalyst relatively to the MAN yield. It has been shown that the promotors increase the catalyst specific surface and affect catalyst surface acidity improving the catalyst efficiency.

[1] Zhyznevsky V.: Doctoral thesis. Moscow Chemical-Technological Institute, Moskwa 1982.

[2] Zhyznevsky V., Roksana M., Kozharsky V and Kucher R.: Dop. Nats.Akad.Nauk URSR B, 1991, 3, 118.

[4] Zhyznevsky V., Gumenetskiy V., Bazhan L. and Maikova S.: Zh. Phys. Khimii, 2001, 75, 1782.

[5] McClennon A. and Harnsberger H.: J. Coll. Interf. Sci., 1967, 23, 577.

[6] Chernykh S. (Ed.): Novye Processy Organicheskogo Sinteza. Khimiya, Moskwa 1989.

[7] Ai M.: Shokubai Catalyst, 1976, 18, 17.

[8] Ai M.: J. Catalysis, 1978, 52, 16.

[9] Kostynyk A. and Nikolenko M.: Chem. & Chem. Techn., 2011, 5, 89.