Diffusion Behaviour of Trivalent Metal Ions in Aqueous Solutions
Affiliation:
Department of Chemistry, University of Coimbra, 3004-535 Coimbra, Portugal
vlobo@ci.uc.pt
DOI:
https://doi.org/10.23939/chcht05.02.133
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Abstract:
Trivalent metal ions have a relevant impact on different kinds of industry; for example, indium(III) and europium(III) ions are of practical importance in the development of new semiconductors and luminescent probes, respectively. Transport properties of ions and salts in aqueous solutions are important physico-chemical parameters allowing a better understanding of the behaviour of these ions in the solution and so, helping to describe better the mechanism of processes taking place in their presence. However, the measurement of those transport properties is complicated due to the occurrence of hydrolysis; that may justify the scarcity of e.g. diffusion data for aqueous solutions of europium(III) and indium(III) chlorides. In this study mutual diffusion coefficients for aqueous solutions of InCl3 and EuCl3 in a concentration range from 0.002 moldm−3 to 0.01 moldm−3 at 298.15 K are reported. The open-ended conductometric capillary cell was used. The results are discussed on the basis of the Onsager-Fuoss and Pikal models.
References:
[1] Bünzli J. and Choppin G. (Eds.): Lanthanide Probes in Life, Chemical and Earth Sciences: Theory and Practice. Elsevier, Amsterdam 1989.
[2] Lochhead M., Wamsley P. and Bray K.: Inorg. Chem., 1994, 33, 2000.
https://doi.org/10.1021/ic00087a041
[3] Williams R.: Struct. Bonding, 1982, 50, 79.
https://doi.org/10.2466/pr0.1982.50.1.79
[4] Costa D., Ramos M., Burrows H. et al.: Chem. Phys., 2008, 352, 241.
https://doi.org/10.1016/j.chemphys.2008.06.014
[5] New E., Parker D., Smith D. and Walton J.: Curr. Opin. Chem. Biol., 2010, 14, 238.
https://doi.org/10.1016/j.cbpa.2009.10.003
[6] Valente A., Burrows H., Pereira R. et al.: Langmuir, 2006, 22, 5625.
https://doi.org/10.1021/la060285e
[7] Zhou Y., Zhou L., Wu J. et al.: Thin Solid Films, 2010, 518, 4403.
https://doi.org/10.1016/j.tsf.2010.02.031
[8] He P., Wang H., Liu S. et al.: Electrochem. Solid State Lett., 2009, 12, 6.
https://doi.org/10.1149/1.3008700
[9] Dong H., Liu Y., Wang D. et al.: Nanotechnology, 2010, 21, 395.
[10] Lochhead M. and Bray K.: J. Non-Cryst. Solids, 1994, 170, 143.
https://doi.org/10.1016/0022-3093(94)90040-X
[11] Mukherjee D., Ray P. and Chowdhury U.: Tetrahedron, 2001, 57, 7701.
https://doi.org/10.1016/S0040-4020(01)00699-8
[12] Loh U., Pei J. and Cao G.: Chem. Commun., 1996, 1, 1819.
https://doi.org/10.1039/cc9960001819
[13] Zhang J. and Li C.: J. Org. Chem., 2002, 67, 3969.
https://doi.org/10.1021/jo020131d
[14] Kantam M., Roy M., Roy S. et al.: J. Mol. Catal. A, 2007, 265, 244.
https://doi.org/10.1016/j.molcata.2006.10.021
[15] Zhang J. and Li C.: J. Org. Chem., 2002, 67, 3969.
https://doi.org/10.1021/jo020131d
[16] Chavan N., Naik P., Nayak S. and Kusurkar R.: Synth. Commun., 2010, 40, 2941.
https://doi.org/10.1080/00397910903340702
[17] Ciulla T., Criswell M., Snyder W. and Small W.: Br. J. Ophthalmol., 2005, 89, 113.
[18] Granqvist C. and Hultaker A.: Thin Solid Films, 2002, 411, 1.
https://doi.org/10.1016/S0040-6090(02)00163-3
[19] Shi S. and Ma D.: Phys. Status Solid. A, 2009, 206, 2641.
https://doi.org/10.1002/pssa.200925114
[20] Kim J. and Choi Y.: Thin Solid Films, 2009, 517, 5084.
https://doi.org/10.1016/j.tsf.2009.03.093
[21] Dutta D., Sudarsan V., Srinivasu P. et al.: J. Phys. Chem. C, 2008, 112, 6781.
https://doi.org/10.1021/jp800576y
[22] Agar J. and Lobo V.: J. Chem. Soc., Faraday Trans. I, 1975, 71, 1659.
https://doi.org/10.1039/f19757101659
[23] Marcus Y.: Chem. Rev., 1988, 88, 1475.
https://doi.org/10.1021/cr00090a003
[24] Robinson R. and Stokes R. (Eds.): Electrolyte Solutions, 2nd edn., Butterworths, London 1959.
[25] Harned H. and Owen B. (Eds.): The Physical Chemistry of Electrolytic Solutions, 3rd edn., Reinhold Pub. Corp., New York 1964.
[26] Mauerhofer E., Zhernosekov K.and Rosch F.: Radiochim. Acta, 2003, 91, 473.
https://doi.org/10.1524/ract.91.8.473.20009
[27] Campbell A.: Can. J. Chem., 1973, 51, 3006.
https://doi.org/10.1139/v73-447
[28] Pikal M.: J. Phys. Chem., 1971, 75, 663.
https://doi.org/10.1021/j100675a011
[29] Lobo V., Ribeiro A. and Andrade S.: Ber. Buns. Phys. Chem., 1995, 99, 713.
https://doi.org/10.1002/bbpc.19950990504
[30] Baes C. and. Mesmer R. (Eds.): The Hydrolysis of Cations, John Wiley & Sons: New York 1976.
[31] Gordon A.: J. Chem. Phys., 1937, 5, 522.
https://doi.org/10.1063/1.1750069
[32] Lobo V. and Ribeiro A.: Corros. Prot. Mat., 1994, 13, 18.
[33] Lobo V. and Ribeiro A.: Port. Electrochim. Acta, 1995, 13, 41.
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