Error message

  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).

Dielectric Behavior of SBS/Polyaniline Thermally Processable Blends

Fernando G. Souza Jr.1, 2, Bluma G. Soares1, Fabiola Silveira1, N.M. Renukappa3, Siddaramaiah1, 4
Affiliation: 
1 Instituto de Macromoléculas, Centro de Tecnologia, Universidade Federal do Rio de Janeiro, Cidade Universitária, Rio de Janeiro, Brasil 2 Programa de Engenharia Civil, COPPE, Centro de Tecnologia, Universidade Federal do Rio de Janeiro, Cidade Universitária, Rio de Janeiro, Brasil 3 Department of Electronics & Communication Engineering, Sri Jayachamarajendra College of Engineering, Mysore, India 4 Department of Polymer Science & Technology, Sri Jayachamarajendra College of Engineering, Mysore, India fgsj@ufrj.br
DOI: 
https://doi.org/10.23939/chcht12.04.441
AttachmentSize
PDF icon full_text.pdf661.85 KB
Abstract: 
Styrene–butadiene–styrene triblock copolymer (SBS) blends were prepared using different weight ratios of conducting polyaniline (PANI). Several electrical properties such as volume resistivity, dielectric constant, dissipation factor and alternating current conductivity of the blends were studied pointing to understand the influence of different parameters like PANI concentration, frequency, and temperature on these properties. The prepared materials present a slight reduction in volume resistivity as a function of temperature, being useful in conditions where the temperature control is hard. More than this, dielectric constant tests allowed inferring that among tested samples, the one filled with 45 wt % of PANI is potentially able to be used in the electromagnetic dissipation field. Finally, the alternating current tests allowed to prove that the electrical conduction of the blend is mainly dominated by ionic transportation. Therefore, prepared materials can be considered as a strategic, low-cost, environmentally friendly material which can be used in various border fields.
References: 

[1] Melad O., Jarur M.: Chem. Chem. Technol., 2016, 10, 41. https://doi.org/10.23939/chcht10.01.041
[2] Yatsyshyn M., Makogon V., Reshetnyak O. et al.: Chem. Chem. Technol., 2016, 10, 429. https://doi.org/10.23939/chcht10.04.429
[3] Thorat S., Kulkarni M., Thorat G.: Chem. Chem. Technol., 2015, 9, 143. https://doi.org/10.23939/chcht09.02.143
[4] Souza Jr F., da Silva A., de Oliveira G. et al.: Ind. Crops Prod., 2015, 68, 97. https://doi.org/10.1016/j.indcrop.2014.09.032
[5] Souza Jr F., Soares B., Mantovani G. et al.: Polymer, 2006, 47, 2163. https://doi.org/10.1016/j.polymer.2006.01.033
[6] Souza Jr F., Soares B., Siddaramaiah et al.: Mater. Sci. Eng. A, 2008, 476, 240. https://doi.org/10.1016/j.msea.2007.05.099
[7] Liao C., Zhang M., Yao M. et al.: Adv Mater., 2015, 27, 7493. https://doi.org/10.1002/adma.201402625
[8] Mokhtari F., Salehi M., Zamani F. et al.: Text. Prog., 2016, 48, 119. https://doi.org/10.1080/00405167.2016.1201934
[9] Souza Jr F., Pinto J., Soares B.: Eur. Polym. J., 2007, 43, 2007. https://doi.org/10.1016/j.eurpolymj.2007.02.037
[10] Kumar V., Yokozeki T., Goto T., Takahashi T.: Polymer, 2016, 86, 129. https://doi.org/10.1016/j.polymer.2016.01.054
[11] Ferreira S., da Silva A., Souza Jr. F. et al.: J. Biobased Mater. Bioenerg., 2014, 8, 578. https://doi.org/10.1166/jbmb.2014.1478
[12] Souza Jr F., Soares B., Dahmouche K.: J. Polym. Sci. B, 2007, 45, 3069. https://doi.org/10.1002/polb.21305
[13] Khatoon H., Ahmad S.: J. Ind. Eng. Chem., 2017, 53, 1. https://doi.org/10.1016/j.jiec.2017.03.036
[14] Malti A., Tu D., Edberg J. et al.: Org. Electron., 2017, 50, 304. https://doi.org/10.1016/j.orgel.2017.07.043
[15] Stejskal J., Bober P., Trchová M. et al.: Synthetic Met., 2017, 224, 109. https://doi.org/10.1016/j.synthmet.2016.12.029
[16] Mehra N., Mu L., Ji T. et al.: Compos. Sci. Technol., 2017, 151, 115. https://doi.org/10.1016/j.compscitech.2017.08.010
[17] Souza Jr F., Michel R., Soares B.: Polym. Test., 2005, 24, 998. https://doi.org/10.1016/j.polymertesting.2005.08.001
[18] Qi S., Craig D.: Adv. Drug. Deliv. Rev., 2016, 100, 67. https://doi.org/10.1016/j.addr.2016.01.003
[19] Murariu M., Dubois P.: Adv. Drug. Deliv. Rev., 2016, 107, 17. https://doi.org/10.1016/j.addr.2016.04.003
[20] Rafique I., Kausar A., Anwar Z., Muhammad B.: Polym. Plast. Technol. Eng., 2016, 55, 312. https://doi.org/10.1080/03602559.2015.1070874
[21] Aïssa B., Habib M., Abdul-Hafidh E. et al.: Int. J. Mater. Eng. Innovat., 2015, 6, 185. https://doi.org/10.1504/IJMATEI.2015.072207
[22] Sousa A., Vilela C., Fonseca A. et al.: Polym. Chem., 2015, 6, 5961. https://doi.org/10.1039/C5PY00686D
[23] Drakopoulos S., Karger-Kocsis J., Kmetty Á. et al.: Carbohydr. Polym., 2017, 157, 711. https://doi.org/10.1016/j.carbpol.2016.10.036
[24] Saba N., Paridah M., Jawaid M.: Constr. Build. Mater., 2015, 76, 87. https://doi.org/10.1016/j.conbuildmat.2014.11.043
[25] Das A., Sallat A., Böhme F. et al.: ACS Appl. Mater. Interface., 2015, 7, 20623. https://doi.org/10.1021/acsami.5b05041
[26] Imbernon L., Oikonomou E., Norvez S., Leibler L.: Polym. Chem., 2015, 6, 4271. https://doi.org/10.1039/C5PY00459D
[27] Yu B-C., Jung J-W., Park K., Goodenough J.: Energ. Environ. Sci., 2017, 10, 86. https://doi.org/10.1039/C6EE02770A
[28] Hamsan M., Shukur M., Kadir M.: Ionics, 2017, 23; 3429. https://doi.org/10.1007/s11581-017-2155-1
[29] Zeglio E., Schmidt M., Thelakkat M. et al.: Chem. Mater., 2017, 29, 4293. https://doi.org/10.1021/acs.chemmater.7b00474
[30] Suriani A., Nurhafizah M., Mohamed A. et al.: J. Mater. Sci., 2017, 52, 6611. https://doi.org/10.1007/s10853-017-0897-9
[31] George N., Bipinbal P., Bhadran B. et al.: Polymer, 2017, 112, 264. https://doi.org/10.1016/j.polymer.2017.01.082
[32] Li L., Zhao P., Luo Y. et al.: RSC Adv., 2017, 7, 1093. https://doi.org/10.1039/C6RA26155H
[33] Kim H., Ahn K., Lee S.: Polymer, 2017, 110, 187. https://doi.org/10.1016/j.polymer.2017.01.007
[34] García-Uriostegui L., Pineda-Torres G., López-Ramírez S. et al.: Polym. Eng. Sci., 2017, 57, 1214. https://doi.org/10.1002/pen.24499
[35] Yin Q., Wen Y., Jia H. et al.: J. Mater. Sci., 2017, 52, 10814. https://doi.org/10.1007/s10853-017-1251-y
[36] Qi X., Xiu H., Wei Y. et al.: Compos. Sci. Technol., 2017, 139, 8. https://doi.org/10.1016/j.compscitech.2016.12.007
[37] Perrin F., Oueiny C.: React. Funct. Polym., 2017, 114, 86. https://doi.org/10.1016/j.reactfunctpolym.2017.03.009
[38] Souza Jr F., Pinto J., de Oliveira G., Soares B.: Polym. Test., 2007, 26, 720. https://doi.org/10.1016/j.polymertesting.2007.03.004
[39] Souza Jr F., Soares B., Siddaramaiah et al.: Polymer, 2006, 47, 7548. https://doi.org/10.1016/j.polymer.2006.08.026
[40] Souza Jr F., Soares B.: Polym. Test., 2006, 25, 512. https://doi.org/10.1016/j.polymertesting.2006.01.014
[41] Souza Jr F., Soares B., Pinto J.: Macromol. Mater. Eng., 2006, 291, 463. https://doi.org/10.1002/mame.200500406
[42] Souza Jr F., Sirelli L., Michel R. et al.: J. Appl. Polym. Sci., 2006, 102, 535. https://doi.org/10.1002/app.24280
[43] Grove T., Masters M., Miers R.: Am. J. Phys., 2005, 73, 52. https://doi.org/10.1119/1.1794757
[44] Souza Jr F., Oliveira G., Anzai T. et al.: Macromol. Mater. Eng., 2009, 294, 739. https://doi.org/10.1002/mame.200900111
[45] Bohren C.: Am. J. Phys., 2017, 85, 165. https://doi.org/10.1119/1.4975385
[46] Xiang T., Zheng Q., Qin S.: IEEE Trans. Dielectr. Electr. Insul., 2017, 24, 1197. https://doi.org/10.1109/TDEI.2017.005956
[47] Matsouka D., Vassiliadis S., Mitilineos S. et al.: J. Text Inst., 2017, 109, 1. https://doi.org/10.1080/00405000.2017.1330174
[48] Luo X., Wang J., Dooner M., Clarke J.: Appl. Energ., 2015, 137, 511. https://doi.org/10.1016/j.apenergy.2014.09.081
[49] Bhavani G., Ganesan S., Selvasekarapandian S. et al.: Ionics, 2016, 22, 581. https://doi.org/10.1007/s11581-015-1565-1
[50] Baskey H., Johari E., Akhtar M.: IEEE Trans. Electromagn. Compat., 2017, 59, 1060. https://doi.org/10.1109/TEMC.2016.2639060
[51] Abdalla M.: Prog. Electromagn. Res. Lett., 2013, 39, 63. https://doi.org/10.2528/PIERL13022207
[52] Wang Y., Chen Y., Zhou Y., Fu H.: DEStech. Trans. Comput. Sci. Eng., 2016. https://doi.org/10.12783/dtcse/iceiti2016/6153
[53] Bhadra S., Singha N., Khastgir D.: Curr. Appl. Phys., 2009, 9, 396. https://doi.org/10.1016/j.cap.2008.03.009
[54] Samet M., Levchenko V., Boiteux G. et al.: J. Chem. Phys., 2015, 142, 194703. https://doi.org/10.1063/1.4919877
[55] Yousefi N., Sun X., Lin X. et al.: Adv. Mater., 2014, 26, 5480. https://doi.org/10.1002/adma.201305293
[56] Rogti F., Ferhat M.: J. Electrost., 2014, 72, 91. https://doi.org/10.1016/j.elstat.2013.11.012
[57] Yu X., Yi B., Liu F., Wang X.: React. Funct. Polym., 2008, 68, 1557. https://doi.org/10.1016/j.reactfunctpolym.2008.08.009
[58] Chaloupka A., Wedel A., Taha I. et al.:alysis. Mater. Sci. Forum., 2015, 825-826, 944. https://doi.org/10.4028/www.scientific.net/MSF.825-826.944
[59] Saba N., Jawaid M., Alothman O., Paridah M.: Constr. Build. Mater., 2016, 106, 149. https://doi.org/10.1016/j.conbuildmat.2015.12.075
[60] Shukla N., Thakur A., Shukla A., Marx D.: Int. J. Electrochem. Sci., 2014, 9, 7644.
[61] Amin A., Ahmed E., Sabaa M. et al.: Polym Bull., 2016, 73, 147. https://doi.org/10.1007/s00289-015-1477-2