Error message

  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/

Degradation of polymers in aggressive media. Kinetic approach

Gennady Zaikov and Marina Artsis
N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences 4 Kosygin str., 119334 Moscow, Russia
PDF icon full_text.pdf252.66 KB
The degradation of polymers in aggressive media is a complex physico-chemical process including adsorption, diffusion and the dissociation of chemically unstable bonds. The course of degradation has a number of special features, which are linked both with the specific structure of polymeric materials and with specific kinetics of reactions in solids

[1] Emanuel N. and Buchachenko A.: Chemical physics of degradation and stabilization of polymers. VSP International Science Publ., Utrecht 1982.
[2] Bochkov A. and Zaikov G.: Chemistry of the glycosidic bonds. Formation and cleavage. Pergamon Press, Oxford 1979.
[3] Razumovskii S. and Zaikov G.: Ozone and its reactions with organic compounds. Elsevier, Amsterdam 1984.
[4] Emanuel N., Zaikov G. and Maizus Z.: Oxidation of organic compounds. Medium effects in radical reactions. Pergamon Press, Oxford 1984.
[5] Afanasiev V. and Zaikov G.: V oblasti kataliza. Mir, Moskva 1979.
[6] Moiseev Yu. and Zaikov G.: Chemical resistance of polymers in reactive media. Plenum Press, New York 1987.
[7] Zaikov G., Iordanskii A. and Markin V.: Diffusion of electrolytes in polymers. VNU Science Press, Utrecht 1988.
[8] Minsker K., Kolesov S. and Zaikov G.: Degradation and stabilization of polymers on the base of vinylchloride. Pergamon Press, Oxford 1988.
[9] Aseeva R. and Zaikov G.: Combustion of polymer materials. Karl Hanser Verlag, Munchen 1986.
[10] Popov A., Rapoport N. and Zaikov G.: Oxidation of stressed polymers. Gordon & Breach, New York 1991.
[11] Entelis S. and Tiger R.: Kinetika reakcij v gydkoi phase. Khimiya, Moskva 1973.
[12] Danckwerts P.: Trans. Faraday Soc., 1950, 46, 300.
[13] Carslow H. and Jaeger J.: Conduction of heat in solids. Oxford University Press, London 1947.
[14] Crank J.: The mathematics of diffusion. Oxford University Press, London 1956.
[15] McGregor R. and Peters R.: J. Soc. Dyers Colour, 1965, 81, 393.
[16] Fridriksberg D.: Kurs koloidnoi khimii. Khimiya, Leningrad 1974.
[17] Livshits V.: Vysokomol. Soedin. A, 1972, 14, 394.
[18] Shen M. and Sever M.: J. Mater. Sci., 1972, 7, 741.
[19] Lososki S. and Cobbs W.: J. Polym. Sci., 1959, 36, 21.
[20] Vatrow G., Ravens D. and Ward J.: Polymer, 1962, 3, 17.
[21] Lebedev Ya.: Kinet. Katal., 1967, 8, 245.
[22] Bershtein V. and Egorova L.: Vysokomol. Soedin. A, 1977, 19, 1260.
[23] Hosemann R.: J. Appl. Phys., 1963, 34, 25.
[24] Haworth S. et al.: Carbohydr. Res., 1969, 10, 1.
[25] Rowland S. and Roberts E.: J. Polym. Sci. A-l, 1972, 10, 2447.
[26] Be Miller J.: Adv. Carbohydr. Chem., 1967, 22, 25.
[27] Markin V.: PhD thesis, Moscow 1974.
[28] Schmidt P. and Schneider B.: Collect. Czech. Chem. Commun., 1966, 31, 1896.
[29] Chang M., Pound T. and Manley R.: J. Polym. Sci., 1973, 11, 399.
[30] Benson S.: Foundations of chemical kinetics, McGraw-Hill, New York 1960.
[31] Pudov V. and Buchachenko A.: Uspehi Khim., 1970, 39, 130.
[32] Kooyman E. and Strang A.: Recl. Trav. Chim., 1953, 72, 329.
[33] Griva A. and Denisov E.: Dokl. Akad. Nauk SSSR, 1974, 219, 640.
[34] Polishchuk Ya. and Zaikov G.: Multicomponent transport in polymer system for controllable release. Gordon and Breach, Newark 1996.
[35] Iordanski A., Rudakova T. and Zaikov G.: Interaction between polymers and chemical and biological media, VSP Sci. Publ., Zeist 1995.