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Control of Thermochemical Transformations of Components of Coal-Based Binders

Olexandr Borisenko1, Fedir Cheshko1, Leonid Bannikov1, Natalia Holik1, Natalia Ponomarenko2
Affiliation: 
1 State Enterprise "Ukrainian State Research Institute for Carbochemistry" (SE "UKHIN"), 7 Vesnina St., Kharkiv, 61023, Ukraine 2 National Technical University "Kharkiv Polytechnic Institute", 2 Kyrpychova St., Kharkiv, 61002, Ukraine zd@ukhin.org.ua
DOI: 
https://doi.org/10.23939/chcht18.03.442
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Abstract: 
The possibility of considering coal pitch as a material suitable for research modeling the processes of thermochemical transformations of the plastic mass of coal carbonization and their interaction with the solid carbon phase is analyzed. The possibilities of controlling the properties of coal pitch and blast furnace coke during its production with the help of aprotic acid additives in the presence of a co-catalyst are shown.
References: 

[1] Arani, H.F.; Mirhabibi, A.R.; Collins, S.; Daroughegi, R; Khalife Soltani, A.; Naghizadeh, R.; Riahi-Noori, N..; Aghababazadeh, R.; Westwood A. Enhancement in Graphitization of Coal Tar Pitch by Functionalized Carbon Nanotubes. RSC Adv. 2017, 7, 5533–5540. https://doi.org/10.1039/C6RA25441A
[2] Chesko, F.F.; Borisenko, A.L.; Martynova, A.Yu.; Shmalko, V.M.; Zelenskii, O.I. The Possibility of Reducing the Carcinogenicity of Coal Tar Electrode Pitches. Pet. Coal [Online] 2018; 60, 584–591. https://www.vurup.sk/wp-content/uploads/2018/06/PC_4_2018_Chesko_29.pdf (accessed May 31, 2018).
[3] Kovalev, E.T.; Cheshko, F.F.; Ponomarenko, N.V. The Use of Coke–Chemical Materials to the Regulation of the Electrode Coal Tar Pitch Quality. Pet. Coal [Online] 2021, 63, 317–323. https://www.vurup.sk/wp-content/uploads/2021/03/PC-X_Chesko_227-002.pdf (accessed May 31, 2018).
[4] Cheshko, F.F., Shustykov, V.I. Katalitychnyy vplyv na hrupovyy ta khimichnyy sklad kam'yanovuhilʹnoho peku. In Problemy katalizu u vuhlekhimiyi; Zbirnyk naukovykh prats AN Ukrainy; Naukova dumka: Kyiv, 1992; pp 289–291.
[5] Crespo, J.L.; Arenillas, A.; Vina, J.A.; García, R.; Snape, C.E.; Moinelo, S.R. Effect of the Polymerization with Formaldehyde on the Thermal Reactivity of a Low-Temperature Coal Tar Pitch. Energy Fuels 2005, 19, 374–381. https://doi.org/10.1021/ef0498768
[6] Wang, Y.; Zhou, Q.; Zhao, Q; Qu, S.; Zhang, Y. Study on Relationships between Coal Microstructure and Coke Quality during Coking Process. Processes 2023, 11, 724. https://doi.org/10.3390/pr11030724
[7] Nesterenko, L.L.; Biryukov, Yu.V.; Lebedyev, V.A. Osnovy khimii ta fizyky horyuchykh kopalyn; Vyshcha shkola: Kyiv, 1987.
[8] Liu, Yu.-Ch.; Hung, Yu.-H.H.; Sutarsis, Ch.-Ch. H.; Ni, Ch.-Sh.; Liu, T.-Yi.; Chang, J.-K.; Chen, H.-Y. Effects of Surface Functional Groups of Coal-Tar-Pitch-Derived Nanoporous Carbon Anodes on Microbial Fuel Cell Performance. Renew. Energy 2021, 171, 87–94. https://doi.org/10.1016/j.renene.2021.01.149
[9] Sarkar, A.; Kocaefe, D.; Kocaefe, Y.; Bhattacharyay, D.; Sarkar, D.; Morais, B.; Chabot, J. Coke-Pitch Interactions During Anode Preparation. Fuel 2014, 117A, 598–607 https://doi.org/10.1016/j.fuel.2013.09.015
[10] Lee, S.-H.; Roh, J.-S. Changes in Functional Groups and Crystal Structure of Coal Tar Pitch with Respect to Carbonization Temperature. Crystals 2024, 14, 1–13. https://doi.org/10.3390/cryst14020122.
[11] Imangazy, A; Smagulova, G; Kaidar, B; Mansurov, Z; Kerimkulova, A; Umbetkaliev, K; Zakhidov, A; Vorobyev, P; Jumadilov, T. Compositional Fibers Based on Coal Tar Mesophase Pitch Obtained by Electrospinning Method. Chem. Chem. Technol. 2021, 15, 403–407. https://doi.org/10.23939/chcht15.03.403
[12] Marsh, H.; Neavel, R.C. Carbonization and Liquid-crystal (Mesophase) Development. 15. A common Stage in Mechanisms of Coal Liquefaction and of Coal Blends for Coke Making. Fuel 1980, 59, 511–513. https://doi.org/10.1016/0016-2361(80)90179-9
[13] Kim, J.-H.; Hwang, H.-I.; Im, J.-S. Coal Carbonization: Formation, Properties and Relevance of Microstructures in Resultant Cokes. Materials 2023, 16, 4084. https://doi.org/10.3390/ma16114084
[14] Bégin, D.; Alain, E.; Furdin, G.; Marêché, F. Pyrolysis of Coal Tar Pitch and its Mixtures with a Graphite-FeCl3 Intercalated Compound. Influence of Heating Rate and GIC Concentration. Fuel 1995, 74, 139–146. https://doi.org/10.1016/0016-2361(95)92646-N
[15] Odian, G. Principles of Polymerization, 4th ed.; Wiley-Interscience: Hoboken, NJ, 2004.
[16] Chen, L.; Guo, F.; Wu, J.; Li, P.; Zhang, Y. Research on Coal Tar Pitch Catalytic Oxidation and Its Effect on the Emission of PAHs during Co-Carbonation with Coal. Catalysts 2021, 11, 1–15. https://doi.org/10.3390/catal11121428
[17] Tulepov, M; Sassykova, L; Kerimkulova, A; Tureshova, G; Abdrakova, F; Zhapekova, A; Sultanova, Z; Spanova, G; Tolep, D; Gabdrashova, Sh; Baiseitov, D. Preparation of Briquettes on the Basis of Sub-Standard Coal of Kazakhstan Fields. Chem. Chem. Technol. 2022, 16, 118–125. https://doi.org/10.23939/chcht16.01.118
[18] Greenwood, N.N.; Earnshaw, A. Chemistry of the Elements; Elsevier, 2012.
[19] Chemist's Handbook; V. II; STPH of Chem. Lit, 1951.
[20] Kaftan, Yu.S; Drozdnik, I.D.; Miroshnichenko, D.V.; Bidolenko, N.B.; Ryshchenko, A.I. Relationship between Organic and Mineral Parts of Coal Blend and “Hot” and “Cold” Coke Strength. Journal of Coal Chemistry 2007, 3–4, 3–13.
[21] Galushko, A.A.; Lysik, N.A.; Miroshnichenko, D.V.; Litvinenko, O.V. Spectrometrical Analysis for the Determination of the Chemical Composition of Ash of Coal Concentrates (Blends) at PJSC "EVRAZ YUZKOKS". Journal of Coal Chemistry 2017, 4, 3–11.