Conductivity and Interparticle Interactions in the Solutions of 1-1 Electrolytes in Propylene Carbonate in the Wide Range of Temperatures

Tatyana Chernozhuk and Oleg Kalugin
Affiliation: 
V. N. Karazin Kharkov National University 4 Svobody Sq., 61022 Kharkov, Ukraine tanya.chernozhuk@gmail.com
DOI: 
https://doi.org/10.23939/chcht10.01.009
AttachmentSize
PDF icon full_text.pdf307.96 KB
Abstract: 
Results of conductometric investigations of solutions of several 1-1 electrolytes in propylene carbonate in the range of temperatures from 298 to 398 K are presented. Using the expanded Lee-Wheaton equation of electric conductivity, constants of ionic association are defined. It is determined that LiClO4 in propylene carbonate is a non-associated electrolyte. In order to account on the dynamics of ionic solvation, separation into ionic components is made.
References: 

[1] Xu K.: Chem. Rev., 2004, 104, 4303.
https://doi.org/10.1021/cr030203g

[2] Lvov A.: Sorovsky Osvitniy Zh., 2001, 7, 45.

[3] Jansen M. and Yeager H.: J. Phys. Chem., 1973, 77, 3089.
https://doi.org/10.1021/j100644a013

[4] McDonagh P. and Reardon J.: J. Solut. Chem., 1996, 25, 607.
https://doi.org/10.1007/BF00973089

[5] Barthel J., Gores H.-J. and Kramp L.: J. Phys. Chem., 1996, 100, 3671.
https://doi.org/10.1021/jp951946b

[6] Safonova L., Pacaciya B. and Kolker A.: Zh. Fiz. Khimii, 1994, 62, 262.

[7] Mukherjee L., Boden D. and Lindauer R.: J. Phys. Chem., 1970, 74, 1942.
https://doi.org/10.1021/j100704a020

[8] Koshel N., Likhina A., Pinielle I. et al.: Electrokhim., 1986, 22, 1181.

[9] Salomon M. and Plichta E.: Electrochim. Acta, 1984, 29, 731.
https://doi.org/10.1016/0013-4686(84)80007-9

[10] Reardon J.: Electrochem. Acta, 1987, 32, 1595.
https://doi.org/10.1016/0013-4686(87)90011-9

[11] Salomon M. and Plichta E.: Electrochim. Acta., 1983, 28, 1681.
https://doi.org/10.1016/0013-4686(83)85236-0

[12] Salomon M. and Plichta E.: Electrochim. Acta., 1985, 30, 113.
https://doi.org/10.1016/0013-4686(85)80068-2

[13] Mishustin A.: Zh. Fiz. Khimii, 1996, 70, 836.

[14] Webber A.: J. Electrochem. Soc., 1991, 138, 2586.
https://doi.org/10.1149/1.2087287

[15] Christie A. and Vincent C.: J. Phys. Chem., 1996, 100, 4618.
https://doi.org/10.1021/jp952597o

[16] D'Aprano A., Salomon M. and Iammarino M.: J. Electroanal. Chem., 1996, 403, 245.
https://doi.org/10.1016/0022-0728(95)04310-1

[17] Barthel J., Gores H. and Schmeer G.: Ber. Bunsenger Phys. Chem., 1979, 83, 911.
https://doi.org/10.1002/bbpc.19790830908

[18] Hojo M., Miyauchi Y., Tanio A. et al.: J. Chem. Soc. Faraday Trans., 1991, 87, 3847.
https://doi.org/10.1039/ft9918703847

[19] Miyauchi Y., Hojo M., Moriyama H. et al.: J. Chem. Soc. Faraday Trans., 1992, 88, 3175.
https://doi.org/10.1039/ft9928803175

[20] Catul J., Angel J., Maneeley H. et al.: J. Electrochem. Soc., 1975, 122, 319.
https://doi.org/10.1149/1.2134207

[21] He X. et al.: J. Phys. Chem. B., 2005, 109, 23141.
https://doi.org/10.1021/jp055233x

[22] Ue M.: J. Electrochem. Soc., 1994, 141, 3336.
https://doi.org/10.1149/1.2059336

[23] Schmelzer N., Einfeldt J. and Grigo M.: Wiss. Z. UNI ROSTOCK, 1990, 39, 41.

[24] Zana R., Desnoyers J., Perron G. et al.: J. Phys. Chem., 1982, 86, 3996.
https://doi.org/10.1021/j100217a022

[25] Krumgalts B.: J. Chem. Soc. Faraday Trans. I., 1983, 79, 571.
https://doi.org/10.1039/f19837900571

[26] Barthel J., Wahter R. and Gores H.-J.: Modern Aspects of Electrochem., 1979, 13, 18.

[27] Barthel J., Feuerlein F., Neueder R. et al.: J. Solut. Chem., 1980, 9, 209.
https://doi.org/10.1007/BF00648327

[28] Kalugin O. and Vyunnik I.: Zh. Obsh. Khimii, 1989, 59, 1628.

[29] Lee W. and Wheaton R.: J. Chem. Soc. Faraday Trans II., 1978, 74, 743.
https://doi.org/10.1039/F29787400743

[30] Pethybridge A. and Taba S.: J. Chem. Soc. Faraday Trans I., 1980, 76, 368.
https://doi.org/10.1039/f19807600368

[31] Kalugin O. and Vyunnik I.: Zh. Khim. Fiziki, 1991, 10, 708.

[32] Kalugin O., Vyunnik I. and Nur-Eddin I.: Zh. Strukt. Khimii, 1992, 33, 105.

[33] Frohlich G.: Theory of Dielectrics, Clarendon Press, Oxford 1949.

[34] Evans D., Tominaga T., Hubbard J. et al.: J. Phys. Chem., 1979, 83, 2669.
https://doi.org/10.1021/j100483a025

[35] Hubbard J. and Onsager L.: J. Chem. Phys., 1977, 67, 4850.
https://doi.org/10.1063/1.434664

[36] Hubbard J.: J. Chem. Phys., 1978, 68, 1649.
https://doi.org/10.1063/1.435931

[37] Kalugin O., Lebed A. and Vyunnik I.: J. Chem. Soc. Faraday Trans., 1998, 94, 2103.
https://doi.org/10.1039/a802735h

[38] Payne R. and Theodorow I.: J. Phys. Chem., 1972, 76, 2892.
https://doi.org/10.1021/j100664a019

[39] Usacheva T. and Shakhparonov M.: Sovr. Problemy Fiz. Khimii, 1980, 12, 259.

[40] Rodnikova M.: Zh. Fiz. Khimii, 1993, 67, 275.

[41] Pereligin I., Itkulov I. and Krauze A.: Zh. Fiz. Khimii, 1992, 66, 573.

[42] Pereligin I., Klimchuk M. and Smolskaya E.: Zh. Fiz. Khimii, 1987, 41, 101.