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Conductivity and Interparticle Interactions in the Solutions of 1-1 Electrolytes in Propylene Carbonate in the Wide Range of Temperatures

Tatyana Chernozhuk and Oleg Kalugin
Affiliation: 
V. N. Karazin Kharkov National University 4 Svobody Sq., 61022 Kharkov, Ukraine tanya.chernozhuk@gmail.com
DOI: 
https://doi.org/10.23939/chcht10.01.009
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Keywords:

Abstract: 
Results of conductometric investigations of solutions of several 1-1 electrolytes in propylene carbonate in the range of temperatures from 298 to 398 K are presented. Using the expanded Lee-Wheaton equation of electric conductivity, constants of ionic association are defined. It is determined that LiClO4 in propylene carbonate is a non-associated electrolyte. In order to account on the dynamics of ionic solvation, separation into ionic components is made.
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