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Thermodynamic Properties of Solutions of the Acrylic Acid in 1,2-Dichloroethane and Acetic Acid

Valentin Serheyev, Yuri Kos and Yuri Van-Chin-Syan
Affiliation: 
Lviv Polytechnic National University, 12, St. Bandery str.,79013 Lviv, Ukraine; vsergeev@.polynet.lviv.ua
DOI: 
https://doi.org/10.23939/chcht05.02.123
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Keywords:

Abstract: 
The saturated vapor pressure of the acrylic acid solutions in 1,2-dichloroethane and acetic acid was measured by static tensimetric method in the temperature range of 295 to 355 K. The composition of the equilibrium phases as well as the activity coefficients (γ1 and γ2) were received from the experimental measurements of the temperature-dependent saturated vapor pressure. Then we used the temperature and concentration dependent activity coefficients to calculate the excess thermodynamic functions of the solutions mixing (HE, GE, SE).
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