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Thermodynamic Properties of Solutions of the Acrylic Acid in 1,2-Dichloroethane and Acetic Acid

Valentin Serheyev, Yuri Kos and Yuri Van-Chin-Syan
Affiliation: 
Lviv Polytechnic National University, 12, St. Bandery str.,79013 Lviv, Ukraine; vsergeev@.polynet.lviv.ua
DOI: 
https://doi.org/10.23939/chcht05.02.123
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Abstract: 
The saturated vapor pressure of the acrylic acid solutions in 1,2-dichloroethane and acetic acid was measured by static tensimetric method in the temperature range of 295 to 355 K. The composition of the equilibrium phases as well as the activity coefficients (γ1 and γ2) were received from the experimental measurements of the temperature-dependent saturated vapor pressure. Then we used the temperature and concentration dependent activity coefficients to calculate the excess thermodynamic functions of the solutions mixing (HE, GE, SE).
References: 

[1] Van-Chin-Syan Yu., Kochubei V., Sergeev V. et al.: Zh. Phys. Khim., 1996, 70, 1789.

[2] Halatin I., Van-Chin-Syan Yu., Kochubei V. et al.: Voprosy Khim. i Khim. Techn., 2005, 1, 55.

[3] Halatin I., Van-Chin-Syan Yu., Kochubei V. et al.: Voprosy Khim. i Khim. Techn., 2006, 4, 28.

[4] Pilugin A., Konopleva Т. and Luzyanina G.: Zh. Prykl. Khimii, 1983, 56, 1723.

[5] Eck B. and Maurer G.: Fluid Phase Equilibrium, 2003, 2, 281.
https://doi.org/10.1016/S0378-3812(03)00128-6

[6] Tu C.-H., Wu Y.-S. and Liu T.-L.: Fluid Phase Equilibrium, 1997, 135, 97.
https://doi.org/10.1016/S0378-3812(97)00054-X

[7] Chubarov G., Danov S. and Balashov A.: Deposited Doc., ONIITEHIM Cherkasy (Ukraine), 10.03.89, N259-hp89.

[8] Chubarov G., Danov S. and Efremov R.: Zh. Prykl. Khimii, 1974, 47, 2130.

[9] Chubarov G., Danov S. and Balashov A.: Zh. Prykl. Khimii, 1989, 62, 331.

[10] Frolov A., Loginova М. and Saprykina А.: Zh. Prykl. Khimii, 1962, 10, 2282.

[11] Danov S., Obmelyuhina T. and Chubarov G.: Zh. Prykl. Khimii, 1990, 63, 596.

[12] Dolgopolov А., Obmelyuhina T. and Danov S.: Zh. Prykl. Khimii, 1991, 64, 1994.

[13] Wilson G.: J. Amer. Chem. Soc., 1964, 86, 135.

[14] Renon H. and Prausnitz J.: Ind. Eng. Chem., 1968, 2, 220.
https://doi.org/10.1021/i260026a011

[15] Abrams D. and Prausnitz J.: AIChE J., 1975, 21, 116.
https://doi.org/10.1002/aic.690210115

[16] Belousov V. and Morachevsky A.: Khimiya i Termodinamica Rastvorov, Khimiya, Leningrad 1964.

[17] Belousov V. and Morachevsky A.: Teplota Gydkikh Smesei. Khimiya, leningrad 1970.

[18] Boublik T., Fried V. and Hala E.: The Vapour Pressure of Pure Substances. Elsevier, Amsterdam 1973.

[19] Makitra R., Turovsky A. and Zaikov G.: Correlation Analysis in Chemistry Solutions., Brill Academic Publishers, New York 2004.
https://doi.org/10.1201/b12185

[20] Makitra R., Turovsky A. and Zaikov G.: Liquid Phase Correlation Analysis in the Chemistry of Solutions. Nova Science Publishers, New York 2007.

[21] Dimroth K., Reichardt C. and Siepmann T.: Leibigs Annallen der Chemie, 1963, 661, 1.
https://doi.org/10.1002/jlac.19636610102

[22] Mayer U., Gerder W. and Gutman V.: Monatshefte für Chemie, 1977, 108, 1.
https://doi.org/10.1007/BF01046463

[23] Kos Yu.: PhD thesis, Lviv Polytechnic National University, Ukraine 2010.

[24] Kos Yu., Serheyev V. and Van-Chin-Syan Yu.: Visnyk Lvivskogo Nationalnogo Universitety. Khimiya, 2010, 51, 256.