Eriochrome Black T – a New Analytical Reagent for Spectrophotometric Determination of Sulphanilamides
Affiliation:
1State Scientific-Research Control Institute of Veterinary Medicinal Products and Feed Additives,
11, Donetska str., 79019 Lviv, Ukraine
2Ivan Franko National University of Lviv, Faculty of Chemistry, Department of Analytical Chemistry,
6, Kyryla and Mefodiya str., 79005 Lviv, Ukraine; boiko_maria@ukr.net
DOI:
https://doi.org/10.23939/chcht09.04.401
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Abstract:
Optimal conditions of the sulphanilamides diazonium salts interaction with o,o'-dihydroxysubstituted azo dye eriochrom black T have been defined. Therefrom the method of spectrophotometric determination of ten sulphanilamides in finished medicinal forms has been developed. This method is based on the azocoupling reaction of the sulphanilamide diazo salt with one of the products of the redox destruction of azo dye with formation of a colored azo compound. This method is characterized by the wide linearity range (from 3 to 64 µg/ml depending on the detectable sulphanilamide), simplicity, rapidity (duration of analysis is under 30 min), and reproducibility (Sr ~ 0.040).
References:
[1] Vaid F., Aminuddin M. and Mehmood K.: Pakist. J. Pharm. Sci., 2004, 17, 77.
[2] Klokova E. and Dmitrienko S.: Vestn. Mosk. Univ. Serіya 2. Khimiya, 2008, 49, 339.
[3] Evgeniev M., Garmonov S., Shakirova L. et al.: Zh. Anal. Khimii, 2000, 55, 888.
[4] Ogoda Onah J. and Eromi Odeiani J.: J. Pharmaceut. Biomed, 2002, 30, 851.
[5] Vijaya Raja G., Bala Sekaran C., Siva Kumari P. et al.: Orient. J. Chem., 2008, 24, 1021.
[6] Sharma S., Neog M. and Dabhi D.: Int. Pharm. Sci. Drug. Res., 2010, 2, 204.
[7] Nagaraja P., Yathirajan H., Raju C. et al.: Il Farmaco, 2003, 58, 1295.
[8] Nagaraja P., Sunitha K., Vasantha R. et al.: Eur. J. Pharm. Biopharm, 2002, 53, 187.
[9] Nagaraja P., Naik S., Sherestha A. et al.: Acta Pharm., 2007, 57, 333.
[10] Nagaraja P., Sunitha K., Vasantha R. et al.: Indian J. Pharm. Sci., 2002, 644, 391.
[11] Vijaya Raja G., and Siva Kumari P.: Orient. J. Chem., 2008, 24, 1021.
[12] Nagaraja P., Yathirajan H., Kallanchira Sunitha R. et al.: J. AOAC Іnt., 2002, 85, 234.
[13] Sabry S.: Anal. Lett, 2006, 39, 2591.
[14] Amin A., El-Sayed G. and Issa Y.: Microchem. J, 1995, 51, 367.
[15] Boiko M., Vrublevska T., Korkuna O. et al.: Spectrochim. Acta A, 2011, 79A, 325.
[16] Boiko M., Vrublevska T., Korkuna O. et al.: Vіsn. Lvіv. Univ. Serіya Khіm., 2011, 52, 174.
[17] Boiko M., Vrublevska T., Korkuna O. et al.: Voprosy Khimii i Khim. Techn., 2012, 116.
[18] Boiko M., Vrublevska T., Korkuna O. et al.: Zavodskaya Laboratorіya, 2012, 28, 19.
[19] Stokolosa L., Kostyuk І. and Boiko M.: 13-a Vseukrainska Conf. Studentіv ta Aspіrantіv "Suchasnі Problemy Khіmії", Ukraine, Kyiv 2012, 171.
[20] Ryan A., Laurieri N., Westwood I. et al.: J. Mol. Biol., 2010, 400, 24.
[21] Zhou H., Wu X., Meng F. et al.: Spectrochim. Acta A, 2011, 78, 681.
[22] Ghosh S.: Chem. Phys. Lett, 2010, 500, 295.
[23] Zhu M., Huang X. and Shen H.: Talanta, 2001, 53, 927.
[24] El-Didamony A. and Moustafa M.: Arabian J. Chem., 2010, 3, 265.
[25] Aydogmus Z.: Acta. Pharm. Sci., 2006, 48, 45.
[26] Sivasubramanian L., Kasi Sankar V., Sivaraman V. et al.: Indian J. Pharm. Sci., 2004, 66, 799.
[27] Rahman N., Khan N.A. and Azmi S.: Farmaco, 2004, 59, 47.
[28] Narayana Reddy M., Tulaja Rani G., Prasada Rao K. et al.: Indian J. Pharm. Sci., 1997, 59, 188.
[29] Patil D. and Chafle D.: Asian J. Chem., 2007, 19, 3253.
[30] Li Y., Dong L., Wang W. et al.: Anal. Biochem, 2006, 354, 64.
[31] Shuwei L., Na L., Fenglin Z. et al.: Fenxi Huaxue, 2002, 30, 732.
[32] The Merck Index. 11th edn. Ranway, Merck&Co., Inc., N.J. 1989.
[33] European Pharmacopoeia (Eur. Ph.). 7th edn. Council of Europe, Strasbourg 2010.
[34] Yatusevich A., Tolkach N., Yatusevich I. et al.: Lekarstvennye Sredstva v Veterinarii. Spravochnik. Minsk 2006.
[35] Agronomov A.: Izbrannye Glavy Organicheskoi Khimii: Ucheb. Posobie dlya Vuzov. Khimiya, Moskva 1990.
[36] Tsollinger G.: Khimiya Azokrasitelei. Goskhimizdat, Leningrad 1960.
[37] Stepanov B.: Vvedenie v Khimiyu i Tekhnologiyu Organicheskikh Krasitelei. Khimiya, Moskva 1977.
[38] Venkataraman K.: Khimiya Sinteticheskikh Krasitelei. T. 1. Goskhimizdat, Leningrad 1956.
[39] Venkataraman K.: Khimiya Sinteticheskikh Krasitelei. T. 3. Khimiya, Leningrad 1974.
[40] Venkataraman K.: Analiticheskaya Khimiya Sinteticheskikh Krasitelei. Khimiya, Leningrad 1979.
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