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1,3-butadiene and methacrylonitrile obtaining using oxidative conversion of C4 olefins over Fe-Te-Mo-Ox catalyst promoted with BaCl2

Volodymyr Gumenetskiy, Svitlana Maikova and Vyacheslav Zhyznevskiy
DOI: 
https://doi.org/10.23939/chcht01.01.031
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Abstract: 
The effect of BaCl2 promotor on the catalytic properties of Fe-Te-Mo-Ox catalyst of joint oxidative dehydration and oxidative amonolysis of C4 olefins has been examined. The optimal composition of promoted catalyst has been established taking into consideration methacrylonitrile and butadiene yields. The process kinetics has been investigated
References: 

[1] Zhyznevskiy V., Roksana M., Kozharskiy V. and Kucher R.: Dopovidi Akademii Nauk USSR, 1991, 3, 118.

[2] Ghenassia E. and Germain J.: Bull.Soc.Chem.France, 1975, 3, 731.

[3] Stergiov L., Gilot B. and Lagueric C.: Chem.Eng.J., 1983, 26, 201.
https://doi.org/10.1016/0300-9467(83)80015-X

[4] Margolis L.: Geterogennoe cataliticheskoe okiskenie uglevodorodov. Leningrad, 1967.