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Method for Obtaining Isothermal Diagrams of the Liquid - Vapor Equilibrium for the System as Dimethyl Zinc - Dimethyl Telluride

Serhiy Gerasymchuk1, Ihor Poliuzhyn1, Valentyn Serheyev1, Tetiana Hnativ1
Affiliation: 
1 Lviv Polytechnic National University 12 S. Bandery St., 79013 Lviv, Ukraine sergii.i.gerasymchuk@lpnu.ua
DOI: 
https://doi.org/10.23939/chcht17.03.469
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Abstract: 
According to the obtained experimental temperature dependences of the saturated vapor pressure on dimethylzinc – dimethyltelluride solutions with dimethylzinc content of 50.0 and 70.32 mol. %, isothermal sections (280, 290, 300, 310, and 320 K) were made. For the dimethylzinc – dimethyltelluride system based on a limited set of experimental data for the “liquid-vapor” equilibrium, the vapor composition was calculated according to the Duhem – Margules equation, as well as the partial pressures and the distribution coefficient.
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