Error message

  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Unparenthesized `a ? b : c ? d : e` is deprecated. Use either `(a ? b : c) ? d : e` or `a ? b : (c ? d : e)` in include_once() (line 1439 of /home/science2016/public_html/includes/bootstrap.inc).
  • Deprecated function: Array and string offset access syntax with curly braces is deprecated in include_once() (line 3557 of /home/science2016/public_html/includes/bootstrap.inc).

Anomalous Sorption of Yttrium Ions by the Mutual Activated Hydrogels in the Interpolymer System of Poly(Methacrylic Acid) and Poly(4-Vinylpyridine)

Talkybek Jumadilov1, Bakytgul Totkhuskyzy2, Aldan Imangazy1, Juozas Gražulevičius3
Affiliation: 
1 Bekturov Institute of Chemical Sciences, 106 Sh. Valikhanov St., 050010 Almaty, Kazakhstan. 2 Kazakh National Women's Teacher Training University, 114 Gogol St., 050000 Almaty, Kazakhstan. 3 Kaunas University of Technology, 73 K. Donelaičio St., 44249 Kaunas, Lithuania. imangazy.aldan@mail.ru
DOI: 
https://doi.org/10.23939/chcht17.01.052
AttachmentSize
PDF icon full_text.pdf329.91 KB

Keywords:

Abstract: 
This paper considers the effect of mutual activation of poly(methacrylic acid) (PMAA) and poly-(4 vinylpyridine) (P4VP) hydrogels during their remote interaction on the degree of yttrium ions sorption from an aqueous medium. Electrochemical properties were studied by conductometry and pH measurements to predict the activation possibility of these hydrogels. pH measurements showed that at 0.1 hour, the pH values were the lowest, indicating a high content of H+ ions in the aqueous solution. An increase in the interaction time to 24 hours leads to an increase in pH values, indicating a decrease in the content of H+ ions in the solution. The dependences of the specific electrical conductivity were studied. The experiments showed that the maximum values were observed at the ratios of 3 : 3 and 1 : 5 (gPMAA : gP4VP), which coincided with the result of pH measurements. The obtained results indicate the significant changes occurred in the electrochemical and conformational values of the initial macromolecules in the interpolymer system. Our research confirms the presence of remote interaction between hydrogels and their mutual activation.
References: 

[1] Jumadilov, T.K.; Abilov, Zh.A.; Kaldayeva, S.S.; Himersen, H.; Kondaurov, R.G. Ionic Equillibrium and Conformational State in Intergel System Based on Polyacrylic Acid and Poly-4-Vinylpyridine Hydrogels. Journal of Chemical Engineering and Chemistry Research 2014, 1, 253-261.
https://doi.org/10.17265/2161-6221/2014.06.002

[2] Imangazy, A.M.; Jumadilov, T.K.; Kondaurov, R.G.; Zhora, A.D. "Remote Interaction" Effect of Polymer Hydrogels on Samar-ium Ions Sorption; Proceedings of XXI Mendeleev congress on general and applied chemistry; S.-P., 9-13 September 2019; 154.

[3] Alimbekova, B.T.; Korganbayeva, Zh.K.; Himersen, H.;

Kondaurov, R.G.; Jumadilov, T.K. Features of Polymethacrylic Acid and Poly-2-Methyl-5-Vinylpyridine Hydrogels

Remote Interaction in an Aqueous Medium. J. Chem. Chem. Eng. 2014, 8, 265-269.

[4] Jumadilov, T.; Shaltykova, D.; Suleimenov, I. Anomalousion Exchange Phenomenon. In The Proceedings of the Austrian - Slovenian Polymer Meeting 2013; Žigon, M.; Teja Rajšp, T., Eds.; Centre of Excellence PoliMaT: Ljubljana, 2013; p 51.

[5] Jumadilov, T.K.; Kondaurov, R.G. Features of Selective

Sorption Of Lanthanum From Solution, Which Contains Ions Of Lanthanum And Cerium By Intergel System Hydrogel

Of Polymethacrylic Acid: Hydrogel Of Poly-2-Methyl-5-Vinylpyridine. In Chemistry and industrial techniques for chemical engineers; Haghi, A.K.; Pogliani, L.; Ribeiro A.F., Eds.; AAP press, 2020; pp 149-174.

[6] Jumadilov, T.; Yskak, L.; Imangazy, A.; Suberlyak, O. Ion Exchange Dynamics in Cerium Nitrate Solution Regulated by Remotely Activated Industrial Ion Exchangers. Materials 2021, 14, 3491. https://doi.org/10.3390/ma14133491
https://doi.org/10.3390/ma14133491

[7] Jumadilov, T. Electrochemical and Conformational Behaviour of Intergel Systems Based on the Rare Crosslinkedpolyacid and

Polyvynilpyrydines. Proceedings of the Conference of Lithuanian Chemical Society; Lithuania, Kaunas, 2014; pp 226-229.

[8] Jumadilov, Т.К.; Kondaurov, R.G. Self-organization of polymer hydrogels of polyacrylic acid in intergel systems in cerium ions sorption process. Chemical Journal of Kazakhstan 2018, 2,

254-262.

[9] Jumadilov, Т.K.; Kondaurov, R.G.; Khakimzhanov, S.A.; Him-ersen, H.; Yeskaliyeva, G.К. Influence of Initial State

of Hydrogels on Self-Organization of Polymer Networks of Polymethacrylic Acid and Poly-4-Vinylpyridine at their Remote

Interaction in an Aqueous Medium. Chemical Journal of Kazakh-stan 2018, 1, 47-53.

[10] Jumadilov, T.K.; Kosunov, A.O.; Kopbayeva, M.P.;

Kondaurov, R.G.; Imangazy, A.M.; Utesheva, A.A.; Zhora, A.D. Impact of Initial State of Polymer Structures of KU-2-8 And Poly-4-Vinylpyridine on Ionization in Intergel System. Proceed. 6th

International Caucasian Symposium on Polymers and Advanced Materials; Batumi, Georgia 17-20 July, 2019; 54.

[11] Jumadilov, T.; Kondaurov, R.; Imangazy, A.; Myrzakhmetova, N.; Saparbekova, I. Phenomenon of Remote Interaction and

Sorption Ability of Rare Cross-linked Hydrogels of Polymethacrylic Acid and Poly-4-vinylpyridine in Relation to Erbium Ions. Chem. Chem. Technol. 2019, 13, 451-458. https://doi.org/10.23939/chcht13.04.451
https://doi.org/10.23939/chcht13.04.451

[12] Totkhuskyzy, B.; Jumadilov, T.K.; Gražulevicius, J.V. Some Peculiarities of the Interaction of Scandium and Yttrium Ions with Activated Hydrogels. Proceedings from the International sympo-sium on specialty polymers; Kazakhstan, Karaganda, 2019, 104.

[13] Jumadilov, T.K.; Malimbayeva, Z.B.; Yskak, L.K.; Myr-zahmetovа, N.O.; Imangazy, A.; Suberlyak, O.V. Sorption Activity of Interpolymer Systems and Molecularly Imprinted

Polymers Based on Vinyl Monomers in Relation to Rare-Earth And Transition Metal Ions. In Book of Abstracts of VІІI International Scientific-Technical Conference "Advance in petroleum and gas industry and petrochemistry" APGIP-8, Ukraine, Lviv, May 18-23, 2020; Lviv Polytechnic Publishing House, 2020; pp 212-215.

[14] Jumadilov, T.K.; Malimbayeva, Z.B.; Khimersen, Kh.; Saparbekova, I.S.; Imangazy, A.M.; Suberlyak, O.V. Specific Features of Praseodymium Extraction by Intergel System Based on Polyacrylic Acid and Poly-4-Vinylpyridine Hydrogels. Bulletin of the University of Karaganda - Chemistry 2021, 103, 53-59. https://doi.org/10.31489/2021ch3/53-59
https://doi.org/10.31489/2021Ch3/53-59

[15] Totkhuskyzy, B.; Yskak, L.K.; Saparbekova, I.S.; Myr-zakhmetova, N.O.; Jumadilov, T.K., Gražulevicius, J.V. Features of the Extraction of Yttrium and Lanthanum with an Intergel System Based on Hydrogels of Polyacrylic Acid and Poly-4-Vinylpyridine. Bull. Karaganda Univ. 2020, 97, 60-67. https://doi.org/10.31489/2020Ch1/60-67
https://doi.org/10.31489/2020Ch1/60-67

[16] Suberlyak, O.; Mel'nyk, Y.; Skorokhoda, V. Regularities of Preparation and Properties of Hydrogel Membranes. Mater. Sci. 2015, 50, 889-896. https://doi.org/10.1007/s11003-015-9798-8
https://doi.org/10.1007/s11003-015-9798-8

[17] Yskak, L.K.; Jumadilov, T.K.; Myrzahmetovа, N.O.; Suberlyak O.V. Features of Distance Interaction and Mutual Activation of Hydrogel Polymethacrylic Acid and Anionite AV-17. Proceedings from the International symposium on specialty polymers; Kazakhstan, Karaganda 2019; 106.

[18] Suberlyak, O.V.; Baran, N.M.; Melnyk, Y.Y.; Grytsenko, O.M.; Yatsulchak, H.V. Influence of the Molecular Weight of Polyvinylpyrrolidone on the Physicomechanical Properties of Composite Polyamide Hydrogel Membranes. Mater. Sci. 2020, 55, 758-764. https://doi.org/10.1007/s11003-020-00368-3
https://doi.org/10.1007/s11003-020-00368-3