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Influence of Initiators on the Adhesion Properties of Bitumen Modified by Natural Origin Epoxide

Volodymyr Starchevskyy1, Yurii Hrynchuk1, Pavlo Matcipura1, Volodymyr Reutskyy1
Affiliation: 
1 Lviv Polytechnic National University, 12, Bandera Str., 79013 Lviv, Ukraine vstarchevskyy@gmail.com
DOI: 
https://doi.org/10.23939/chcht15.01.142
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Abstract: 
The article is presenting a modification of bituminous binder with ecological epoxidized rapeseed oil (BERO) in the presence of the initiator (hardener). Adipic acid (AA), maleic anhydride (MA) and polyethylene polyamine (PEPA) were used as the initiators. The effect of modification temperature and, as well as initiator nature, on the bitumen properties was determined. Bitumen modified with BERO was evaluated by the following indicators: softening temperature, penetration, ductility, and adhesion to the glass. The optimal initiator : rapeseed oil epoxide (ERO) : bitumen ratio was found to be 0.15:3:100; it allows obtaining bitumen with improved properties, in particular, adhesive properties increase by 2‒3 times depending on the nature and content of the initiator. To improve the formula composite and evaluation of asphalt mixtures the additional researches will be conducted.
References: 

[1] Airey G.: Fuel, 2003, 82, 1709. https://doi.org/10.1016/S0016-2361(03)00146-7
[2] Demchuk Y., Sidun I., Gunka V. et al.: Chem. Chem. Technol., 2018, 12, 456. https://doi.org/10.23939/chcht12.04.456
[3] Zhang W., Ding L., Jia Z.: Appl. Sci., 2018, 8, 457. https://doi.org/10.3390/app8030457
[4] Pyshyev S., Demchuk Y., Gunka V. et al.: Chem. Chem. Technol. 2019, 13, 212-217. https://doi.org/10.23939/chcht13.02.212
[5] Gunka V., Demchuk Yu., Pyshyev S. et al.: Petrol. Coal, 2018, 60, 1199.
[6] Gunka V., Sidun I., Solodkyy S., Vytrykush N.: Lecture Notes in Civil Eng. Proceedings of CEE 2019. Springer 2019, 47, 420.
[7] Wei J., Zhang Y.: J. Test. Eval., 2012, 40, 1169. https://doi.org/10.1520/JTE20120136
[8] Hrynchuk Y., Sidun I., Gunka V. et al.: Petrol. Coal, 2019, 61, 836.
[9] Nykypanchuk M., Hrynchuk Y., Olchovyk M.: Chem. Chem. Technol. 2013, 7, 467. https://doi.org/10.23939/chcht07.04.467
[10] Hrynchuk Y., Sidun I., Gunka V. et al.: Petrol. Coal, 2020, 62, 836.
[11] Demchuk Y., Gunka V., Pyshyev S. et al.: Chem. Chem. Technol., 2020, 14, 251. https://doi.org/10.23939/chcht14.02.251
[12] Martynyuk M.: Visnyk Prykarpat. Nats. Univ. im. Vasylya Stefanyka, 2014, V, 115. http://nbuv.gov.ua/UJRN/vpnu_chem_2014_18_16.
[13] Chemco System Co., 2012, “Epoxy Asphalt for Orthotropic Steel Bridge Decks,” http://www.chemcosystems.com/epoxy.html (Last accessed June 10, 2011).
[14] Apostolidis P., Liu X., van de Ven M. et al.: J. Transport. Res. Board., 2019, 2673, 551. https://doi.org/10.1177/0361198119835530
[15] Yu L.: Highway, 2004, 3, 56.
[16] Kang Y., Chen Z., Jiao Z., Huang W.: J. Appl. Polym. Sci., 2010, 116, 1678. https://doi.org/10.1002/app.31563
[17] Pan L., Wang Y., Wang C. et al.: Thermoset. Resin, 2011, 26, 33.
[18] Zhou X., Wu S., Liu G., Pan P.: Materials and Structures. Nanjing. 2016, 49, 241. https://link.springer.com/article/10.1617/s11527-014-0491-4
[19] Ivashkiv O, Astakhova O., Shyshchak O. et al.: Chem. Chem. Technol., 2015, 9, 69. https://doi.org/10.23939/chcht09.01.069
[20] Bratychak M., Brostow W., Grynyshyn O., Shyshchak O.: Mater. Res. Innovat., 2003, 7, 167. https://doi.org/10.1007/s10019-003-0243-5
[21] Alabaster D., Herrington P., Waters J.: J. Acoustic. Soc. Am., 2012, 131, 3225. https://doi.org/10.1121/1.4708028
[22] Al Fuhaid A., Lu Q., Luo S.: J. Mater. Civil Eng., 2018, 30, 256. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002383
[23] EN 1427. European Standard. Bitumen and bituminous binders. Determination of the softening point. Ring and Ball method.
[24] EN 1426. European Standard. Bitumen and bituminous binders. Methods of tests for petroleum and its products. Determination of needle penetration.
[25] EN 13587. Bitumen and bituminous binders. Determination of the tensile properties of bituminous binders by the tensile test method.
[26] Pyrig Yan, Galkin A.: Bull. Kharkov Nat. Automobile and Highway Univ., 2019, 1, 202. https://doi.org/10.30977/BUL.2219-5548.2019.86.1.202
[27] http://online.budstandart.com/ua/catalog/doc-page?id_doc=27298